“…Ferroelectric tetragonal PbTiO 3 forms a solid solution with antiferroelectric rhombohedral PbZrO 3 [ 2 , 3 ]. Their dielectric and piezoelectric properties are maximal at around the morphotropic phase boundary (MPB) [ 4 ], and the properties around the MPB have been widely utilized for sensors, ultrasonic motors, and medical transducers [ 5 , 6 , 7 ]. Single crystals of Pb(Mg, Nb)O 3 –PbTiO 3 and Pb(Zn, Nb)O 3 –PbTiO 3 exhibit extraordinary high electromechanical coupling factors because a bridging phase in monoclinic symmetry [ 4 , 8 , 9 , 10 ] is capable of a rotation of P s under electric fields [ 8 , 11 , 12 , 13 , 14 ].…”