Pillararene-inspired arenes: Synthesis, properties and applications compared to the parent macrocycle

Bleus, Sem; Dehaen, Wim

doi:10.1016/j.ccr.2024.215762

Coordination Chemistry Reviews

2024

DOI: 10.1016/j.ccr.2024.215762

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Pillararene-inspired arenes: Synthesis, properties and applications compared to the parent macrocycle

Sem Bleus,

Wim Dehaen

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2024

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Cited by 9 publications

References 200 publications

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Triphenylamine[3]arenes: Streamlining Synthesis of a Versatile Macrocyclic Platform for Supramolecular Architectures and Functionalities

Fang,

Zhang,

Guo

et al. 2024

Angewandte Chemie

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Triphenylamine[3]arenes (TPA[3]s), featuring [16]paracyclophane backbone with alternating carbon and nitrogen bridging atoms, were synthesized through a BF3·Et2O‐catalyzed cyclization reaction using triphenylamine derivatized monomers and paraformaldehyde. This molecular design yielded a series of TPA[3] macrocycles with high efficiency, with their facile derivatizations also successfully demonstrated. On account of the strong electron‐donating properties of the TPA moieties, these TPA[3]s exhibit remarkable delayed fluorescence, and possess a significant affinity for iodine. Furthermore, their inherent three‐fold symmetry rendered TPA[3]s as novel building blocks for the construction of extended frameworks and molecular cages. This advancement expands the versatility of discrete macrocycles into complex architectures, enhancing their applicability across a broad spectrum of applications.

show abstract

Triphenylamine[3]arenes: Streamlining Synthesis of a Versatile Macrocyclic Platform for Supramolecular Architectures and Functionalities

Fang,

Zhang,

Guo

et al. 2024

Angewandte Chemie

View full text Add to dashboard Cite

show abstract

Triphenylamine[3]arenes: Streamlining Synthesis of a Versatile Macrocyclic Platform for Supramolecular Architectures and Functionalities

Fang,

Zhang,

Guo

et al. 2024

Angew Chem Int Ed

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Electrochemical characteristics of composites based on novel asymmetric pillar[5]arene with carbon materials and their potential electrochemical applications

Shamagsumova,

Gayazova,

Shurpik

et al. 2024

J Solid State Electrochem

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Pillararene-inspired arenes: Synthesis, properties and applications compared to the parent macrocycle

Cited by 9 publications

References 200 publications

Triphenylamine[3]arenes: Streamlining Synthesis of a Versatile Macrocyclic Platform for Supramolecular Architectures and Functionalities

Triphenylamine[3]arenes: Streamlining Synthesis of a Versatile Macrocyclic Platform for Supramolecular Architectures and Functionalities

Triphenylamine[3]arenes: Streamlining Synthesis of a Versatile Macrocyclic Platform for Supramolecular Architectures and Functionalities

Electrochemical characteristics of composites based on novel asymmetric pillar[5]arene with carbon materials and their potential electrochemical applications

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