We experimentally clarified the characteristics of forward Brillouin scattering induced by radial acoustic modes (R
0,m
) in large effective area fiber. The measured resonance frequencies of R
0,m
modes were shown to have different sensitivities to acoustic impedance. Then we performed discriminative measurement of temperature and acoustic impedance by selecting a pair of different R
0,m
modes that would achieve the minimum measurement error, where we had successfully achieved small measurement uncertainties of 0.4 °C and 0.03 kg·s–1 · mm–2, respectively.