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This study developed a novel dewatering process coupled with nutrient recovery to raise the resource value of anaerobically digested sludge. The hydration of multicharged anions was proposed to compete with the hydration of hydrophilic organic components (i.e., salting-out effects). Accordingly, phosphate was used as the salting-out agent to improve sludge dewaterability, and simultaneously, it balanced the molar ratio of NH4 +-N and PO4 3–-P in the aqueous phase, which could facilitate the recovery of N/P as struvite from the liquid digestate. The addition of phosphate (70% of its solubility) at the initial sludge pH of 5 could obtain the lowest centrifugally dewatering equilibrium height (h∞) of 0.036 cm and reduce the bound water fraction by 63.5%. For the first time, time-of-flight secondary ion mass spectrometry (ToF-SIMS) in situ identified the phosphorus speciation and microdistribution in anaerobically digested sludge. Additionally, the quartz crystal microbalance with dissipation (QCM-D) analysis confirmed that the organics-phosphate interactions led to a dense water-repelling system of sludge flocs with an increasing rigidity, which mainly contributed to the improved centrifugal dewatering performance. All the above contributions are expected to suggest a promising way for simultaneously recovering N/P, improving dewaterability, and facilitating liquid digestate treatment of anaerobically digested sludge.
This study developed a novel dewatering process coupled with nutrient recovery to raise the resource value of anaerobically digested sludge. The hydration of multicharged anions was proposed to compete with the hydration of hydrophilic organic components (i.e., salting-out effects). Accordingly, phosphate was used as the salting-out agent to improve sludge dewaterability, and simultaneously, it balanced the molar ratio of NH4 +-N and PO4 3–-P in the aqueous phase, which could facilitate the recovery of N/P as struvite from the liquid digestate. The addition of phosphate (70% of its solubility) at the initial sludge pH of 5 could obtain the lowest centrifugally dewatering equilibrium height (h∞) of 0.036 cm and reduce the bound water fraction by 63.5%. For the first time, time-of-flight secondary ion mass spectrometry (ToF-SIMS) in situ identified the phosphorus speciation and microdistribution in anaerobically digested sludge. Additionally, the quartz crystal microbalance with dissipation (QCM-D) analysis confirmed that the organics-phosphate interactions led to a dense water-repelling system of sludge flocs with an increasing rigidity, which mainly contributed to the improved centrifugal dewatering performance. All the above contributions are expected to suggest a promising way for simultaneously recovering N/P, improving dewaterability, and facilitating liquid digestate treatment of anaerobically digested sludge.
Rapid population growth and urbanization have resulted in a multi-fold increase in water consumption over the last few decades, resulting in the generation of large amounts of sewage and sewage sludge that impose severe environmental burdens if not handled properly. Sludge management itself accounts for up to 50% of the total operating costs of wastewater treatment plants (WWTPs). Conventional sludge management practices such as incineration, landfilling, and ocean disposal have been deemed difficult in light of today’s stringent environmental legislation and compliance standards. As a result, progress has been made toward developing more sustainable approaches for sludge management. This study reviews recent advancements in sewage sludge management techniques that not only ensure the safe disposal of sewage sludge but also focus on utilizing the potential of sewage sludge as feedstock for energy and resource recovery. Energy could be recovered by subjecting the pre-treated sludge to controlled anaerobic digestion (AD) to produce biogas or by utilizing the lipid content of the sewage sludge through esterification or direct sludge pyrolysis to produce biodiesel/bio-oil. Heavy metals such as Ag, Au, Cu, Fe, Ga, Cr, and others, as well as nutrients such as N, P, K, Mg, S, and others, could also be recovered. If energy and resource recovery from sewage sludge is practiced on a global scale, it could significantly contribute to global greenhouse gas (GHG) emission reduction. This review discusses the commercially developed and still-under-research technologies for energy and other resource recovery of sewage sludge. Additionally, techniques, along with their limitations and potential measures to improve their yields, are also discussed.
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