Pine pollen derived porous carbon with efficient capacitive deionization performance

Liu, Qilin; Li, Xiaoqin; Wu, Yu; Qing, Miaoqing; Tan, Ge; Xiao, Dan

doi:10.1016/j.electacta.2018.12.072

Cited by 50 publications

(21 citation statements)

References 46 publications

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“…Similar trend regarding specific surface area and adsorption capacity for biomass samples treated at 800, 900 and 1000 °C was found in (Liu et al, 2019) by Liu and his co-workers when testing pine pollen char for capacitive deionization. Authors reported a significant decrease (-38%) in specific surface area when the temperature was raised from 900 °C to 1000 °C, together with a lower ion adsorption.…”

Section: Salt Adsorption Capacitysupporting

confidence: 84%

Evaluation of the optimal activation parameters for almond shell bio-char production for capacitive deionization

Maniscalco

Corrado

Volpe

et al. 2020

Bioresource Technology Reports

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A study on a possible new biomass waste to be used as electrode material for capacitive deionization (CDI) processes was performed. Raw almond shells were pyrolyzed at 800, 900 and 1,000 °C and then activated through CO2. Carbon activation is used to develop porosity inside the material, increasing the specific surface area and the adsorption performances. In this work, authors tried to correlate the effects of pyrolysis and activation temperature on the ion storage capacity. Results from the desalination tests indicated that the best performance in terms of ion adsorption was obtained when the bio-char was activated at the temperature of 900 °C. Brunauer-Emmet-Teller (BET) and Barret-Joyner-Halenda (BHJ) analysis confirmed the trend of the CDI tests, reporting the highest surface area and share of micropore sites for the 900 °C samples. Salt adsorption capacity was found to be in the range of 13.7 to 19.2 mg g -1 .

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Section: Salt Adsorption Capacitysupporting

confidence: 84%

Evaluation of the optimal activation parameters for almond shell bio-char production for capacitive deionization

Maniscalco

Corrado

Volpe

et al. 2020

Bioresource Technology Reports

View full text Add to dashboard Cite

show abstract

“…45 When the conductivity of the solution increases from 50 to 500 ms cm À1 , the electrosorption capacity increases from 6.2 to 26.5 mg g À1 . The electrosorption capacity of the HC-800 electrodes with 500 ms cm À1 of NaCl solution is also higher than for most biochar materials reported in the literature, such as chitosan-based activated carbon, 13 soybean shells, 46 pine pollen, 39 or sugarcane biowaste derived biochars. 14 Regeneration and cycling stability are also important parameters in choosing good CDI electrode materials.…”

Section: Experiments Of Hc-800 Electrode and Cs-800 Electrodementioning

confidence: 74%

“…3 shows that the pore sizes of CS-800 mainly range from 2 nm to 10 nm, while the pore size of HC-800 ranges from 2 nm to 6 nm, which is consistent with previous N 2 adsorption/desorption isotherm analysis results. 39 Table 1 shows the microstructure parameters of CS-800 and HC-800. The specic surface area of HC-800 (833.76 m 2 g À1 ) is 6.59 times that of CS-800 (123.43 m 2 g À1 ).…”

Section: Structure and Morphological Characterizationmentioning

confidence: 99%

Chitin derived biochar for efficient capacitive deionization performance

Feng

Song

et al. 2020

RSC Adv.

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“…Carbons derived from biomass have been studied in many research communities owing to their advantages of being environmentally friendly, renewable, rich, and cheap. Pine‐pollen‐derived carbon has been studied as electrode materials for sodium‐ion batteries, [ 15 ] capacitive deionization, [ 16 ] and supercapacitors [ 17 ] due to its worldwide availability. However, this has not been studied as an electrocatalyst for the OER and ORR.…”

Section: Introductionmentioning

confidence: 99%

Biomass‐Derived P, N Self‐Doped Hard Carbon as Bifunctional Oxygen Electrocatalyst and Anode Material for Seawater Batteries

Kim

Park

Lee

et al. 2021

Adv Funct Materials

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Owing to the demand for low-cost batteries with safety, Na-seawater batteries (SWBs) have received considerable attention as a new energy storage system (ESS). In SWB, it is necessary to use an advanced oxygen evolution/reduction reaction (OER/ORR) catalyst for high energy efficiency (EE) in the cathode and a good sodium storage material for a highly reversible capacity in the anode part. In this study, nanostructured and N and P dual-doped hard carbon is fabricated by simply carbonizing abundant biomass, pine pollen. The oxygen electrocatalytic performance of pine pollen carbon (PPC) for a cathode is confirmed by a seawater half-cell test, which exhibits the lowest overpotential reported among Pt/C (20 wt%) and commercial hard carbon (HC) electrodes. The sodium-storage performance of PPC as an anode active material is tested using a coin-type Na half-cell, which exhibits a higher reversible capacity than that of the HC electrode. To reduce the manufacturing cost, this SWB, comprising both PPC electrodes at the anode and cathode, are fabricated and shown an EE of 74% and a coulombic efficiency (CE) of 98%. This study proposes a low-cost and safe ESS system by utilizing seawater as catholyte, bifunctional (OER/ORR, sodiation/desodiation) electrode configuration, and abundantly available biomass carbon.

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Pine pollen derived porous carbon with efficient capacitive deionization performance

Cited by 50 publications

References 46 publications

Evaluation of the optimal activation parameters for almond shell bio-char production for capacitive deionization

Evaluation of the optimal activation parameters for almond shell bio-char production for capacitive deionization

Chitin derived biochar for efficient capacitive deionization performance

Biomass‐Derived P, N Self‐Doped Hard Carbon as Bifunctional Oxygen Electrocatalyst and Anode Material for Seawater Batteries

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