Pitting corrosion of Type 430 stainless steel under chloride solution droplet

Hastuty, Sri; Nishikata, Atsushi; Tsuru, Tooru

doi:10.1016/j.corsci.2010.02.031

Cited by 123 publications

(83 citation statements)

References 25 publications

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“…This suggests a correlation with the time needed to reach a critical concentration of interfacial chloride that is necessary to fully break down the passive oxide film, 17,18,46 (indicated by red circle in Fig. 2a).…”

Section: Resultsmentioning

confidence: 99%

“…Typically, electrochemical pitting corrosion and crevice corrosion tests are carried out in a representative environment, and the sample surfaces are then examined ex-situ using a variety of different techniques. [16][17][18] Initial pit-formation can be studied in situ by scanning probe imaging techniques such as electrochemical scanning tunneling microscopy (EC-STM), 19 electrochemical atomic force microscopy (EC-AFM) 20 or scanning kelvin probe force microscopy (SKPFM). 21 But even EC-STM and EC-AFM or SKPFM do not always detect pitting corrosion since the initiation sites are sparsely distributed, and just after initiation the subsequent pit propagation cannot be visualized inside the active environment.…”

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confidence: 99%

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Real-Time Monitoring of Aluminum Crevice Corrosion and Its Inhibition by Vanadates with Multiple Beam Interferometry in a Surface Forces Apparatus

Shrestha

Baimpos

et al. 2015

J. Electrochem. Soc.

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Crevice corrosion (CC) of metals remains a serious concern for structural materials. Yet a real-time in situ visualization of corrosion, and its inhibition within a confined geometry, remains challenging. Here, we present how multiple-beam interferometry in a Surface Forces Apparatus can be utilized to directly visualize corrosion processes in real-time and with Ångstrom resolution within welldefined confinement geometries. We use atomically smooth muscovite mica surfaces to form round-shaped ∼1000 μm 2 crevices on aluminum. After exposure to NaCl solutions we can detect and track active sites of aluminum corrosion within this confined geometry. CC of aluminum randomly initiates in the confined crevice mouth, where the distance between apposing surfaces is between 20-300 nm. We can directly track oxide dissolution/formation, and corrosion-rates as well as their retardation due to sodium vanadate inhibitors present in solution. Formation of a compacted oxide layer effectively inhibits CC in 5 mM NaCl solutions with 2.5 mM of added NaVO 3 , while inhibition rapidly breaks down at chloride concentrations above 50 mM. Breakdown of the inhibition-layers is initiated by rapid dissolution of the protective oxide within the confined zone. Our technique may be adapted for monitoring CC, corrosion inside of crack-tips, and evaluation of inhibitor efficiencies in a variety of metals.

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Section: Resultsmentioning

confidence: 99%

mentioning

confidence: 99%

Real-Time Monitoring of Aluminum Crevice Corrosion and Its Inhibition by Vanadates with Multiple Beam Interferometry in a Surface Forces Apparatus

Shrestha

Baimpos

et al. 2015

J. Electrochem. Soc.

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“…El diámetro de las picaduras, así como la densidad y la profundidad, aumentará notablemente con el tiempo. Teniendo en cuenta esta problemática, para este trabajo se han fabricado una serie de probetas de acero AISI 304 en forma de discos de 600 mm de diámetro con distintos espesores, concretamente de 4, 7 y 11 mm.corroborado esta morfología (Hamzah et al, 2013;Hastuty et al, 2010;Szklarska-Smialowska, 1972). Por ejemplo, en la Figura 3, se puede observar la corrosión por picadura con una distribución lineal una vez se han eliminado los productos de corrosión superficiales.…”

Section: Preparación De Probetasunclassified

Detección de la corrosión por picadura en aceros inoxidables empleando ultrasonidos

Rodríguez

Biezma

2014

REVMETAL

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RESUMEN:Los sistemas pasivables, capaces de desarrollar una capa protectora, delgada, adherente y continua sobre el substrato metálico, presentan excelente resistencia a la corrosión ya que dicha capa se produce instantáneamente al reaccionar con el medio. Ahora bien, en determinadas circunstancias, esa capa se puede romper localmente, dando lugar a uno de los ataques más insidiosos que se conocen, corrosión por picadura, que producen unas condiciones químicas locales que aceleran el proceso corrosivo provocando defectos en el material, tanto externos como internos, con una distribución aleatoria en la superficie metálica. En este trabajo se ha planteado el empleo de técnicas de ensayos no destructivas mediante ultrasonidos para detectar este tipo de ataque en un acero inoxidable austenítico AISI 304, con distinta distribución superficial de defectología y profundidades de ataque, que simulan picaduras, tomando como variable fundamental de la onda ultrasónica la amplitud máxima del eco de fondo. SUMMARY:Pitting corrosion detection in stainless steels using ultrasounds. Passive metallic systems are able to develop in a spontaneous way a protective layer on the metallic surface that offers excellent corrosion resistance since really in a physical barrier for the reaction with the environment. However, some factors can break locally this layer, promoting one of the most insidious attack, pitting corrosion, which produces local chemical conditions that favouring the corrosive process causing defects in the material, as externals and internals ones, with a random distribution on the metal surface. In this work, ultrasounds non destructive technique has been employed using as variable the maximum amplitude of the backwall echo in order to detect this type of attack. The material employed is an austenitic stainless steel AISI 304, wherein appear several defectology distributions as superficial such as depths simulating pits.

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“…In marine environments, the temperature drops and relative humidity (RH) rises at night, the moisture in the air may condense and form droplets or a thin solution layer containing chloride ions on metals surface. In contrast, an evaporation process, which increases the chloride ion concentration in the droplets, occurs as the daytime temperature increases and the RH decreases [6] .The chloride ions adsorb on the outer surface of the passive film, permeate through the passive oxide film, and interact with the underlying metal [7,8,9] . In order to understand the corrosion behavior of steel as a function of type of steel and exposure time, the morphologies of the surface, the polarization and pitting potential have been studied on many occasions.…”

Section: Introductionmentioning

confidence: 99%

Evaluation of Corrosion Behaviors of Austenitic Stainless Steel Exposed in Marine Atmosphere of South China Sea

Tong¹,

Liu²,

Zhang³

et al. 2018

Proceedings of the 2018 7th International Conference on Energy, Environment and Sustainable Development (ICEESD 2018)

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Pitting corrosion of Type 430 stainless steel under chloride solution droplet

Cited by 123 publications

References 25 publications

Real-Time Monitoring of Aluminum Crevice Corrosion and Its Inhibition by Vanadates with Multiple Beam Interferometry in a Surface Forces Apparatus

Real-Time Monitoring of Aluminum Crevice Corrosion and Its Inhibition by Vanadates with Multiple Beam Interferometry in a Surface Forces Apparatus

Detección de la corrosión por picadura en aceros inoxidables empleando ultrasonidos

Evaluation of Corrosion Behaviors of Austenitic Stainless Steel Exposed in Marine Atmosphere of South China Sea

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