Efficient
transformation of renewable biomass into chemicals and
biofuels, including liquid biomass-derived nonedible oils to biodiesel,
is of great importance. Developing heterogeneously functional materials
is being deemed as a subject of particular interest to scientists
in selective catalytic chemistry especially for biomass valorization.
In this regard, porous polymers, featuring high surface areas, prominent
stabilities, and chemically adjustable moieties, have attracted extensive
concerns. In this Review, recent developments on the application of
heterogeneously functionalized porous polymeric catalysts of high
performance, including acid/base chemosynthetic organic polymers/natural
biodegradable biopolymers like chitosan, organic–inorganic
hybrid polymeric materials such as functional porous coordination
polymers, and porous polymers immobilized with enzymes for effective
upgrading of oil feedstocks into biodiesel are summarized. Catalytic
protocols using functional polymeric catalysts provide significant
benefits for realizing biorefinery procedures because of the following
reasons: (i) no polluting reagents, (ii) high activities and selectivities,
and (iii) simple and convenient catalyst recycling. Attention has
been drawn, in particular, to understanding the role of acidity/basicity,
hydrophilicity/hydrophobicity, swelling property, and porosity of
polymer materials in biodiesel production through transesterification
and esterification reactions. In addition, plausible reaction mechanisms
are also depicted accordingly, while highlighting the main remaining
challenges and future prospects.