Abstract. Surface treatment of polymers by discharge plasmas has increasingly found industrial applications due to its capability of modifying uniformly the surface without changing the material bulk properties. This work deals with surface modification of polyethylene terephthalate (PET) by a dielectric barrier discharge (DBD) at atmospheric pressure. The treatments were conducted in air, nitrogen or argon plasma. The polymer surface was characterized by contact angle measurement, X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). The results show that the plasma treatment introduces oxygen-and nitrogen-related polar groups on the polymer surface and promotes the surface roughening. Both plasma-induced surface modifications contribute to the enhancement of the polymer wettability.
IntroductionPolymers possess good mechanical and chemical properties; however, their use in various applications involving composite and biomaterials, packing, printing, dying etc, has been restricted due to their poor adhesion properties. Improvement of the adhesion can be accomplished by chemical methods (adding functional groups on the surface) and/or trough introducing micro-or nano-scale roughness on the surfaces. Recently, the classical chemical technologies have been gradually replaced by the environmentally friendly, versatile and low-cost plasma treatment. The atmospheric pressure plasmas are especially attractive as surface modification tools due to their applicability to a variety of substrates, easy scaling-up, quick processing time, and low cost [1].This work describes the surface modification of a PET polymer by atmospheric pressure dielectric barrier discharge DBD. This type of discharge occurs between two planar or cylindrical electrodes provided that at least one of them is covered by a dielectric layer. As a consequence, after the gas breakdown takes place, the charge accumulation on the dielectric surface prevents the corona-to-arc transition. The DBD plasmas have many applications ranging from surface functionalization and grafting [2], improvement of adhesion and hydrophylicity [3], sterilization [4], processing of textile and fabrics [5] and, most recently, the so-called plasma medicine [6].