Edge
structures are low-dimensional defects unavoidable in layered
materials of the transition metal dichalcogenides (TMD) family. Among
the various types of such structures, the armchair (AC) and zigzag
(ZZ) edge types are the most common. It has been predicted that the
presence of intrinsic strain localized along these edges structures
can have direct implications for the customization of their electronic
properties. However, pinning down the relation between local structure
and electronic properties at these edges is challenging. Here, we
quantify the local strain field that arises at the edges of MoS2 flakes by combining aberration-corrected transmission electron
microscopy (TEM) with the geometrical-phase analysis (GPA) method.
We also provide further insight on the possible effects of such edge
strain on the resulting electronic behavior by means of electron energy
loss spectroscopy (EELS) measurements. Our results reveal that the
two-dominant edge structures, ZZ and AC, induce the formation of different
amounts of localized strain fields. We also show that by varying the
free edge curvature from concave to convex, compressive strain turns
into tensile strain. These results pave the way toward the customization
of edge structures in MoS2, which can be used to engineer
the properties of layered materials and thus contribute to the optimization
of the next generation of atomic-scale electronic devices built upon
them.