aerospace and automotive industries. In solid oxide fuel cells, the addition of Sc to the electrolyte improves conductivity and lowers the operating temperature, extending fuel cell life.Despite a crustal abundance of ca. 22 ppm (Rudnick and Gao, 2014), comparable to common elements such as copper or lead, current Sc production is limited to 10 t to 15 t per year (U.S. Geological Survey, 2016). The large ratio of ionic radius to charge of Sc 3+ hinders the concentration of scandium during most geochemical processes (Samson and Chassé, 2016). A notable exception concerns lateritic deposits developed over ultramafic-mafic rocks where Sc concentrations up to 100 ppm make it a potential by-product (Aiglsperger et al., 2016;Maulana et al., 2016). Recently, lateritic deposits with Sc concentrations high enough to mine as a primary product have been reported in Eastern Australia (Jaireth et al., 2014). Among these, the Syerston-Flemington deposit contains about 1350 t of Sc at an average concentration of 434 ppm Sc (Pursell, 2016), providing a century-long resource at the present levels of world consumption.We present the first data on Sc speciation in lateritic deposits by combining quantitative mineralogy, geochemical analysis and X-ray absorption near-edge structure (XANES) spectroscopy on drill-core samples from the lateritic profile of the Syerston-Flemington deposit. The results explain the geochemical conditions required to form such exceptional Sc concentrations and improve our understanding of the geochemical behaviour of this under-explored element.
Geological ContextIn Eastern Australia, lateritic profiles developed under seasonally dry humid tropical climatic conditions that resulted in intensive weathering during the Tertiary; the present occurrences are often erosional remnants of fossil laterite (Milnes et al., 1987). The Syerston-Flemington deposit (Fig. 1a and Table S-1) is part of the lateritic cover developed over the Tout complex, an ultramafic-mafic 'Alaskan-type' intrusive complex in the Lachlan Fold Belt (Johan et al., 1989). Scandium anomalies have been found over a body of nearly pure clinopyroxenite (Fig. S-1), with Sc concentrations (ca. 80 ppm; Table S-3) twice as high as those in typical mantle clinopyroxenites (Samson and Chassé, 2016). Similar concentrations (60 ppm to 80 ppm) occur in other 'Alaskan-type' clinopyroxenites (Burg et al., 2009) and in clinopyroxenes from ocean-island basalts (Dorais, 2015). This suggests the accumulation of clinopyroxene in subvolcanic feeder conduits during fractional crystallisation of a mantle-derived melt. Anomalies of Sc concentration in the parent rock result from specific conditions of formation and are not shared by all ultramafic-mafic bedrocks. Scandium (Sc) has unique properties, highly valued for many applications. Future supply is expected to rely on unusually high-grade (up to 1000 ppm) lateritic Sc ores discovered in Eastern Australia. To understand the origin of such exceptional concentrations, we investigated Sc speciation in one of these d...