“…Heterostructured nanomaterials have gained increased attention because they display multiple functionalities, selectivity, superior catalytic activity, and stability compared to monometallic nanomaterials, also the respective characteristics can be retained. − The catalytic performance of any hetero-nanostructure is highly dependent on several factors, such as compositions, sizes, and shapes. − Among a number of architectures, a core–shell structure formed by supporting metal nanoparticles as islands on the core of another metal substrate stands out due to a series of benefits. − First, the loss of core activity derived from the agglomeration of the shell metal can be dramatically suppressed . Second, the catalytic activity can be guaranteed due to the small size and large specific area of the spatially separated shell metal islands. , In terms of the fabricating methods, the galvanic replacement reaction based on the potential difference is a simple method for fabricating a core–shell structure with metal islands supported on another core metal. − Basically, this method was used to deposit more noble metals with higher reduction potentials on non-noble metals with relatively lower reduction potentials so that several benefits can be achieved. First, the overall cost of catalysts can be reduced because most of the expensive noble metal particles cores can be replaced by inexpensive ones.…”