2023
DOI: 10.1002/cctc.202300644
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PNP‐Pincer Ligands Armed With Methyls: New Tools To Control Sterics and Non‐Innocence

Dilip K. Pandey,
Eugene Khaskin,
Julia R. Khusnutdinova

Abstract: The widespread use of pyridine‐based PNP pincer ligands has inspired the concept of metal‐ligand cooperation (MLC), in which the reactivity at the deprotonated CH2 (or NH) arm of the ligand is proposed to play an important role. Several groups developed a family of methylated PNP‐type pincer ligands with methylated arms which were initially introduced to test the effect of blocking MLC in catalysis, but eventually led to unexpected consequences such as stabilization of unusual oxidation states, beneficial cata… Show more

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