PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO₂ in the presence of silanes

Abstract

Catalytic sustainable transformation of carbon dioxide into valuable fine chemicals with high efficiency is a global challenge even CO2 is an abundant, nontoxic, and sustainable carbon feedstock but one of...

Metal‐Catalyzed Carbonylation Reactions with CO2: An Update

“…In addition, the catalytic conversion of CO 2 into formamides 2 with amines 1 and (MeO) 3 SiH was realized by Peng, Bai and co‐workers in the presence of a Cu‐(PNP) complex containing a PEG chain ( L ) [17] . The process was found to tolerate both primary and secondary aliphatic as well as aromatic amines 1 , including highly encumbered substrates.…”

Ag‐Nanocatalysts Based on Porous Organic Polymers in Chemical Fixation of CO2 for the N‐Methylation and N‐Formylation of Amines

“…Recently, Warner and the group reported N methylation and N formylation with phosphonium salt as a catalyst [13] . Bai and colleagues and Jhung and the group reported selective N methylation and N formylation with PNP‐type ligand and Zr‐based MOF [14–15] . Li and his group reported TiO 2 supported catalyst for the synthesis of N‐formylated and N‐methylated amines [16] .…”

“…[13] Bai and colleagues and Jhung and the group reported selective N methylation and N formylation with PNPtype ligand and Zr-based MOF. [14][15] Li and his group reported TiO 2 supported catalyst for the synthesis of N-formylated and Nmethylated amines. [16] The inherent drawback of the above processes is that the retrieval of the catalyst poses considerable difficulties.…”