1968
DOI: 10.1149/1.2411292
|View full text |Cite
|
Sign up to set email alerts
|

Poisson's Equation as a Condition of Equilibrium in Electrochemical Systems

Abstract: The available analyses of the conditions for equilibrium in electrochemical systems do not consider the electrostatic field as a possible variable. Since there is a voltage difference between the electrodes in an electrochemical system, an electrostatic field must be present, and this field must be considered in the treatment of equilibrium because it affects the internal energy of the system. This paper presents an analysis in which the electric displacement vector is included as a possible variable. The resu… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
2

Citation Types

0
11
0

Year Published

1972
1972
2018
2018

Publication Types

Select...
4
2

Relationship

0
6

Authors

Journals

citations
Cited by 11 publications
(11 citation statements)
references
References 5 publications
0
11
0
Order By: Relevance
“…The performance of the cell can be explained by a series of steps. First, when the PS2 output voltage V PS2 =E ex I=0 (null point) because of the usual condition of uniformity of the electrochemical potential throughout the electrolyte solution [9]. Second, if V PS2 is increased from the null point, then a charge current I=I c flows due to the total source voltage (emf) of ΔE=V PS2 -E ex .…”
Section: Electrostatic-induction Potential-superposed Charge Of Lithimentioning
confidence: 99%
“…The performance of the cell can be explained by a series of steps. First, when the PS2 output voltage V PS2 =E ex I=0 (null point) because of the usual condition of uniformity of the electrochemical potential throughout the electrolyte solution [9]. Second, if V PS2 is increased from the null point, then a charge current I=I c flows due to the total source voltage (emf) of ΔE=V PS2 -E ex .…”
Section: Electrostatic-induction Potential-superposed Charge Of Lithimentioning
confidence: 99%
“…When a cell is open and no current flows, electrochemical potential of ions (ũ, unit in Jmol −1 ) is even throughout in the electrolyte [7]. When a cell is open and no current flows, electrochemical potential of ions (ũ, unit in Jmol −1 ) is even throughout in the electrolyte [7].…”
Section: Electrostatic Energy Conversion In Power Generation Systemmentioning
confidence: 99%
“…The electric field is used in the laws of thermodynamics as an independent intensive factor similar to temperature or pressure [9][10][11][12]. Thus, we wish to show that the electrostatic energy of the electric field can be quasi-statically converted into the chemical energy of the ionic medium (thermodynamic energy), and to derive an equation for such conversion.…”
Section: Internally Self-sustaining Electrostatic Energymentioning
confidence: 99%