This paper proposes a hybrid crop classifier for polarimetric synthetic aperture radar (SAR) images. The feature sets consisted of span image, the H/A/α decomposition, and the gray-level co-occurrence matrix (GLCM) based texture features. Then, the features were reduced by principle component analysis (PCA). Finally, a two-hidden-layer forward neural network (NN) was constructed and trained by adaptive chaotic particle swarm optimization (ACPSO). K-fold cross validation was employed to enhance generation. The experimental results on Flevoland sites demonstrate the superiority of ACPSO to back-propagation (BP), adaptive BP (ABP), momentum BP (MBP), Particle Swarm Optimization (PSO), and Resilient back-propagation (RPROP) methods. Moreover, the computation time for each pixel is only 1.08 × 10−7 s.