We have investigated experimentally and theoretically the spectral distribution and collisional depolarization of laser light near resonant to the Na transition 3 2S1/2~---,3 2P3/2 scattered from a Na/Ar mixture in a cell (nNa ~ 4.0 x 101 o cm 3, nAr ~ 1.0 X 1017 cm-3). In particular, at excitation intensity of ~3mW/mm 2 and bandwidth of <10MHz, intensity I F and linear polarization degree P~ of the D2-fluorescence component of the scattered spectrum have been measured as functions of the laser detuning A2 L from the D2-resonance within two regions: 1) I A 2LI < Doppler-width; 2) 20 > I A 2c[/A/l o > 1. Within the first region the influence of hyperfine splitting as well as pumping of the hyperfine and Zeeman sublevels of 3 2S1/2 was studied in detail. Using an overall, total collision cross section for depolarization of 3 2P3/2 state atoms, calculations on the basis of the theory of redistribution reproduce qualitatively, but in a consistent manner, the experimental functions lr(A 2i.) and Pp(A2L). The possibility to derive differential cross sections from Pv(A2L) is discussed.