Abstract. We calculate X-ray line polarization degrees for cases with axial symmetry using a collisional-radiative magnetic-sublevel atomic kinetics model and the properties of multipole radiation fields. This approach is well-suited for problems where the alignment is determined by the competition between many atomic processes. We benchmark this method against polarization measurements performed at the Livermore electron beam ion trap, and we study the 3-to-2 cascade effects on the polarization of 2-to-1 lines in He-like Fe.