Polarization Reorientation of Carbon Nitride Induced by a Local Bridge Donor for Boosting Photocatalytic H2 Evolution Integrated with Selective Amine Oxidation
Abstract:Polymeric
carbon nitride (PCN) has attracted much attention in
the field of photocatalysis, but the use of PCN is often confined
to internal structures with highly symmetrical heptazine units bridged
by N atoms. Accurate tuning of the positions of heteronuclear atoms
is a meaningful strategy but remains a big challenge. Herein, a catalyst
with PN bonds accurately embedded among the heptazine units
was prepared using a straightforward polymerization method. According
to density functional theory simulation and… Show more
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