Polarographic Reduction of Carbon Dioxide

The Polarographic Observations on Percarbonic Acids and Percarbonates.

“…A typical polarogram showing the phenomena described above is given in figure 1. In figure 2 the previously observed reduction of carbon dioxide (15,16,17) at a half-wave potential of 2.16 v. with respect to the saturated calomel electrode appears in addition to the new wave observed at low potentials.…”

“…Other percarbonic acids could also be expected, such as H2CO5 and H2C2O6. Our previous polarographic studies on carbon dioxide (15,16,17) have shown that, in the absence of oxygen or hydrogen peroxide, the new wave now being discussed is not observed. We are definitely dealing with the reduction of a compound formed by reaction of carbon dioxide with hydrogen peroxide.…”

Organosilicon Polymers. III. Infrared Spectra of the Methylpolysiloxanes

“…Octa(Bands common to all polymers in this series occur at 3.375(8),3.445(H),6.92(W), 7.10(H), 7.16(W), and 7.95(8))9.11 (W) 9.09(W)9. 11 I'M)9.82(8) 9.29(8) 9.25(8) 9.36(8) 9.43(8) 9.47(8) 11.41(W) 11.66(W) 11.68(W) 11.66(W) 11.65(W) 11.64(H) 12.19(W) 12.19 (W) 12.19(W) 12.18(W) 12.29(8) 12.33(8) 12.37(8) 12.42(8) 12.44(8) 12.45(8) Open Chain Polymers 3.380(8) 3.380(8) 3.377(8) 3.375(8) 3.375(8) 3.375(8) 3.375(8) 3.450(M) 6.34(M) 3.450(H) 3.448(H) 3.445(H) 3.445(H) 3.445(H) 3.445(H) 6.94(W) 6.93(W) 6.94(W) 6.93(W) 6.94(W) 6.94(W) 6.93(W) 7.09(H) 7.08(H) 7.09(H) 7.09(H) 7.09(H) 7.09(H) 7.08(H) 7.14(W) 7.14(W) 7.15(VV) 7.15(W) 7.16(W) 7.15(W) 7.15(W) 7.96(8) 7.96(8) 7.95(8) 7.95(8) 7.95(8) 7.95(8) 7.99(8) 8.00(H) 8.00(\V) 9.29(H) 9.26(8) 9.21(8) 9.19(8) 9.16(8) 9.15(8) 9.40(H) 9.47(H) 9.53(W) 9.57(W) 9.48(8) 9.56(8) 9.63(8) 9.68(8) 9.72(8) 9.74(8) 9.77(8) 11.36(W) 11.39(W) 11.40(W) 11.38(VV) 11.41(W) 11.39(W) 11.85(8) 11.87(8) 11.88(8) 11.88(8) 11.89(8) 11.88(8) 11.88(8) 11.85(8) 11.84(8) 12.62(H) 13.17…”

CO2 photoreduction at enzyme-modified metal oxide nanoparticles

“…4,5 A good catalyst either transfers two electrons together (including oxygen atom transfer) or stabilises the CO 2 À intermediate. Electrocatalysts for CO 2 reduction have advanced significantly from the report by Van Rysselberghe et al in 1944 using a dropping mercury cathode, 6 but major challenges remain in terms of…”