Vacuum-deposited thin films of polymethylmethacrylate (PMMA) doped by varying concentrations (2-10 % by weight of polymer) of some 3,5-diaminopyrazole derivatives as dipolar chromophores were prepared to study their relaxation behaviour . Poling of thin films was carried out using multi-point corona-poling technique to orient dipolar chromophores in proper aligned position. Poling and depoling behaviours of these thin films have been investigated by UV/Vis absorption spectra. For each chromophore, poling efficiency was found to increase with poling voltage as well as poling temperature up to a certain limit retaining the properties of thin films. Maximum value of concentration dependent order parameter was obtained at temperature slightly lower than glass transition temperatures of corresponding guesthost matrices. After 300 hrs. of poling under the conditions (5 kV, near Tg, 30 min.), the decayed amounts of order parameters at room temperature were within the range 25-38 % of the initial value for various guest-host systems. Relaxation behaviour of poling-induced chromophore alignment has also been studied at elevated temperature.