Currently,
research has been focusing on printing and laser crystallization
of cyclosilanes, bringing to life polycrystalline silicon (poly-Si)
thin-film transistors (TFTs) with outstanding properties. However,
the synthesis of these Si-based inks is generally complex and expensive.
Here, we prove that a polysilane ink, obtained as a byproduct of silicon
gases and derivatives, can be used successfully for the synthesis
of poly-Si by laser annealing, at room temperature, and for n- and
p-channel TFTs. The devices, fabricated according to CMOS compatible
processes at 350 °C, showed field effect mobilities up to 8 and
2 cm2/(V s) for n- and p-type TFTs, respectively. The presented
method combines a low-cost coating technique with the usage of recycled
material, opening a route to a convenient and sustainable production
of large-area, flexible, and even disposable/single-use electronics.