Poly(ε-caprolactone)-grafted-chitosan copolymers: Synthesis and use as tunable and biodegradable coating for water soluble fertilizers

Boutriouia, El Hassan; El Assimi, Taha; Qayouh, Hicham; Raihane, Mustapha; El Meziane, Abdellatif; Baouab, Mohamed Hassen V.; Youcef, Hicham Ben; El Kadib, Abdelkrim; Lahcini, Mohammed

doi:10.1016/j.reactfunctpolym.2024.105887

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article3

Preprint1

Relationship

Self Cite0

Independent4

Authors

Journals

Cited by 4 publications

References 34 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Tailored and sustainable bio-composite thanks to synergetic interactions of polycaprolactone (PCL) and guar gum derivative

Assimi,

Boutriouia,

Jalit

et al. 2024

J Polym Res

View full text Add to dashboard Cite

Tailored and sustainable bio-composite thanks to synergetic interactions of polycaprolactone (PCL) and guar gum derivative

Assimi,

Boutriouia,

Jalit

et al. 2024

J Polym Res

View full text Add to dashboard Cite

Biopolymer-polyphenol conjugates: Novel multifunctional materials for active packaging

Sahraeian,

Abdollahi,

Rashidinejad

2024

International Journal of Biological Macromolecules

View full text Add to dashboard Cite

Tailored and sustainable bio-composite thanks to synergetic interactions of Polycaprolactone (PCL) and Guar Gum derivative

Assimi,

Boutriouia,

Jalit

et al. 2024

Preprint

View full text Add to dashboard Cite

In this research study, we describe the synthesis of new and tailored bio-composite materials by leveraging the synergistic interaction between polycaprolactone (PCL) and carboxymethyl hydroxypropyl guar gum (CMHPG). The proposed approach involves the in-situ ring opening polymerization (ROP) of ε-caprolactone, enabling the grafting of high molecular weight PCL chains (100 Kg.mol− 1) onto CMHPG using a highly stable tin-based catalyst. The successful covalent association between the hydrophobic PCL chains and the hydrophilic CMHPG polysaccharide was confirmed. In addition, comprehensive structural (FTIR, DLS, contact angle and DRX), thermal (TGA and DSC), and mechanical characterizations were performed to investigate the synergistic effects between PCL and CMHPG. Notably, by precisely controlling the amount of CMHPG filler incorporated during synthesis, we achieved tailored performance in terms of film hydrophobicity and controlled biodegradability kinetics. These findings underscore the significant potential of the developed PCL bio-composites for specialized applications such as coatings, surface engineering, and the production of antifouling or repellent materials.

show abstract

Poly(ε-caprolactone)-grafted-chitosan copolymers: Synthesis and use as tunable and biodegradable coating for water soluble fertilizers

Cited by 4 publications

References 34 publications

Tailored and sustainable bio-composite thanks to synergetic interactions of polycaprolactone (PCL) and guar gum derivative

Tailored and sustainable bio-composite thanks to synergetic interactions of polycaprolactone (PCL) and guar gum derivative

Biopolymer-polyphenol conjugates: Novel multifunctional materials for active packaging

Tailored and sustainable bio-composite thanks to synergetic interactions of Polycaprolactone (PCL) and Guar Gum derivative

Contact Info

Product

Resources

About