Poly[(μ-1,3-thiocyanato-κN,S)(isonicotinato-κN,O)(ethanol-κO)cadmium(II)]

Abstract

Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.004 Å; R factor = 0.026; wR factor = 0.061; data-to-parameter ratio = 20.1.In the crystal structure of the title compound, [Cd(NCS)-(C 6 H 4 NO 2 )(C 2 H 5 OH)] n , the Cd 2+ cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol molecule and two -1,3-bridging thiocyanate anions in a distorted octahedral N 2 O 3 S geometry. The metal cations are -1,3-bridged via thiocyanate anions into chains that are further connected into layers parallel to the ab plane by bridging isonicotinate anions. The layers are stacked along the c axis. The crystal structure is stabilized by O-HÁ Á ÁO hydrogen bonds. Related literature

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