Polyamide 66/poly(2,6-dimethyl-1,4-phenylene oxide) compatibilization with styrene–acrylonitrile–glycidyl methacrylate: rheology, morphology, and mechanical properties

Abstract

During the blending process, Styrene-acrylonitrile-glycidyl methacrylate (SAG) was grafted through in-situ formation of PA66 as a compatibilizer for polyamide 66/poly (2,6-dimethyl-1,4-phenoxy) (PA66/PPO) composites. The compatibilizer has a obvious advantage on the PA66/PPO blends terminal behavior in the dynamic rheological analysis. Moreover, the gap between the PA66 and PPO glass-transition temperatures decreases with the SAG content increasing, which indicates improved compatibility. The morphology of the PA66/PPO/SAG blends was analyzed by scanning electron microscopy, which revealed the particles narrower size distributions and became smaller after adding SAG. In addition, the compatibilization improves the mechanical properties of blends significantly when SAG reached 5 by weight per hundred resins (phr). This is attributed to enhanced interfacial adhesion and finer dispersion morphology. However, when 7 phr of SAG are added, the exceeded compatibilizer produces a limitation on the improvement of the mechanical properties.Our results indicate that the optimal concentration of the compatibilizer, SAG, is between 3 and 5 phr for PA66/PPO (60/40). HIGHLIGHTS•SAG was confirmed to be an efficient reactive compatibilizer for PA66/PPO blends.•The viscoelastic properties of compatibilized changed by the in-situ reaction.•The mechanical properties improved significantly after adding SAG.

Preparation and Properties of PA10T/PPO Blends Compatibilized with SEBS-g-MAH

“…It has favorable characteristics including low D k and D f , water resistance, and good dimensional stability. Consequently, the development of PA/PPO blends has been the subject of extensive investigation [ 18 ]. To date, various blends of aliphatic PA and PPO have been developed by using effective compatibilizers [ 19 , 20 , 21 ].…”