Polyaniline-coated VS4@rGO nanocomposite as high-performance cathode material for magnesium batteries based on Mg2+/Li+ dual ion electrolytes

Jing, Pengcheng; Lu, Huimin; Yang, Wenwen; Cao, Yuan; Xu, Binbin; Cai, Weiping; Deng, Yan

doi:10.1007/s11581-019-03239-3

Cited by 21 publications

(20 citation statements)

References 51 publications

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“…Moreover, the cathode in APC-LiTFSI shows a smaller polarization and higher reversibility than those in APC-LiCl at a high rate (Figure S10b and c). Compared with previously reported cathodes in MLHBs (Figure f and Table S1), NiCo 2 S 4 in the APC-LiTFSI electrolyte represents the best rate performance. ,,,,,− According to calculation of the integral of U discharge and Q specific capacity , an ultrahigh gravimetric energy density of 708 Wh kg –1 (based on the weights of active materials) is achieved at 0.1 A g –1 with a capacity of 746.1 mAh g –1 . Even when the binder and conductive carbon black are included, the electrode exhibits a high energy density of 566 Wh kg –1 (Figure S11a and b).…”

Section: Resultsmentioning

confidence: 81%

A Magnesium/Lithium Hybrid-Ion Battery with Modified All-Phenyl-Complex-Based Electrolyte Displaying Ultralong Cycle Life and Ultrahigh Energy Density

Ding

Han

et al. 2022

ACS Nano

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Magnesium/lithium hybrid-ion batteries (MLHBs) combine the advantages of high safety and fast ionic kinetics, which enable them to be promising emerging energy-storage systems. Here, a high-performance MLHB using a modified all-phenyl complex with a lithium bis(trifluoromethanesulfonyl)imide electrolyte and a NiCo2S4 cathode on a copper current collector is developed. A reversible conversion involving a copper collector with NiCo2S4 efficiently avoids the electrolyte dissociation and diffusion difficulties of Mg2+ ions, enabling low polarization and fast redox, which is verified by X-ray absorption near edge structure analysis. Such combination affords the best MLHB among all those ever reported, with a reversible capacity of 204.7 mAh g–1 after 2600 cycles at 2.0 A g–1, and delivers an ultrahigh full electrode-basis energy density of 708 Wh kg–1. The developed MLHB also achieves good rate performance and temperature tolerance at −10 and 50 °C with a low electrolyte consumption. The hybrid-ion battery system presented here could inspire a broad set of engineering potentials for high-safety battery technologies and beyond.

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Section: Resultsmentioning

confidence: 81%

A Magnesium/Lithium Hybrid-Ion Battery with Modified All-Phenyl-Complex-Based Electrolyte Displaying Ultralong Cycle Life and Ultrahigh Energy Density

Ding

Han

et al. 2022

ACS Nano

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“…The released electrons flow through the external circuit which is responsible for the production of current. During charging, the Mg 2+ gets deintercalated from the polymer cathode and moves into the electrolyte solution, and the cycle repeats. , …”

Section: Magnesium Ion Batteries (Mibs)mentioning

confidence: 99%

“…Insertion and Deinsertion Mechanism. 177,178 Polymer cathode materials have a layered and tunnel-like structure when mixed with inorganic materials like VS 4 @rGO on PANI; these possess definite interlayer spacing which undergoes an insertion and deinsertion mechanism. During discharge, the anode undergoes oxidation as Mg 2+ , moves into the electrolyte solution, and gets inserted into the polymer cathode materials.…”

Section: Magnesium Ion Batteries (Mibs)mentioning

confidence: 99%

“…During charging, the Mg 2+ gets deintercalated from the polymer cathode and moves into the electrolyte solution, and the cycle repeats. 177,178 4.2. Different Polymers Used in Magnesium Ion Batteries.…”

Section: Magnesium Ion Batteries (Mibs)mentioning

confidence: 99%

“…When the current density was increased to 200 mA g −1 , this battery still discharged with 240.4 mAh g −1 and 71.7 mWh g −1 of specific capacity and energy density, respectively. Jing et al 177 hydrothermally synthesized VS 4 @rGO onto it, and they polymerized PANI as a cathode, in an APC (all phenyl complex) and LiCl−APC electrolyte, in a potential range of 0−2.0 V. This showed a high discharge capacity of 200.7 mAh g −1 up to 20 cycles at 100 mA g −1 current density and retained 91.2% after 50 cycles. Here the PANI layer acts as a conductive medium that enhances electron transfer and helps in the insertion and exertion mechanism.…”

Section: Magnesium Ion Batteries (Mibs)mentioning

confidence: 99%

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Advances in Zinc and Magnesium Battery Polymer Cathode Materials

Bose

et al. 2022

ACS Appl. Energy Mater.

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Electrical energy storage is an ever growing and important area of research in a modern technological world. The quest for energy storage materials is always in the limelight of research for the replacement of conventional environmentally toxic metal-based redox-active materials by organic molecules which provides an alternative for rechargeable batteries. Zinc/magnesium-based conducting polymer batteries attracted significant attention due to their high abundance, safety, and cost-effectiveness compared with lithium ion batteries (LIBs). This Review lays out an extensive overview of metal anodes like zinc/magnesium with conducting polymer cathode materials that possess high conductivity and theoretical capacitance. In addition, the complete redox behavior of polymer cathodes, the mechanism, the anode behavior in acidic and alkaline media, the effect of different electrolyte uses and drawbacks, the binders, and the housing of these batteries have been reviewed in detail. The socioeconomic impact, problems associated with dendrite, and passive layer formation with zinc/magnesium polymer cathode batteries, as well as future perspectives, will give a complete overview for the general reader as well as for experts working in these fields.

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Vanadium Tetrasulfide for Next‐Generation Rechargeable Batteries: Advances and Challenges

Yao

Chen

et al. 2022

The Chemical Record

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Alkali metal‐ion batteries (SIBs and PIBs) and multivalent metal‐ion batteries (ZIBs, MIBs, and AIBs), among the next‐generation rechargeable batteries, are deemed appealing alternatives to lithium‐ion batteries (LIBs) because of their cost competitiveness. Improving the electrochemical properties of electrode materials can greatly accelerate the pace of development in battery systems to cover the increasing demands of realistic applications. Vanadium tetrasulfide (VS4) is known as a prospective electrode material due to its unique one‐dimensional atomic chain structure with a large chain spacing, weak interactions between adjacent chains, and high sulfur content. This review summarizes the synthetic strategies and recent advances of VS4 as cathodes/anodes for rechargeable batteries. Meanwhile, we describe the structural characteristics and electrochemical properties of VS4. And we describe in detail its specific applications in batteries such as SIBs, PIBs, ZIBs, MIBs, and AIBs as well as modification strategies. Finally, the opportunities and challenges of VS4 in the domain of energy research are described.

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Polyaniline-coated VS4@rGO nanocomposite as high-performance cathode material for magnesium batteries based on Mg2+/Li+ dual ion electrolytes

Cited by 21 publications

References 51 publications

A Magnesium/Lithium Hybrid-Ion Battery with Modified All-Phenyl-Complex-Based Electrolyte Displaying Ultralong Cycle Life and Ultrahigh Energy Density

A Magnesium/Lithium Hybrid-Ion Battery with Modified All-Phenyl-Complex-Based Electrolyte Displaying Ultralong Cycle Life and Ultrahigh Energy Density

Advances in Zinc and Magnesium Battery Polymer Cathode Materials

Vanadium Tetrasulfide for Next‐Generation Rechargeable Batteries: Advances and Challenges

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