Polyaniline/FeZSM-5 composites – Synthesis, characterization and their high catalytic activity for the oxidative degradation of herbicide glyphosate

Milojević-Rakić, Maja; Bajuk–Bogdanović, Danica; Vasiljević, Bojana Nedić; Rakić, Aleksandra; Škrivanj, Sandra; Ignjatović, Lj. M.; Dondur, V.; Mentus, Slavko; Ćirić‐Marjanović, Gordana

doi:10.1016/j.micromeso.2018.03.019

Cited by 25 publications

(10 citation statements)

References 61 publications

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“…In addition to differences in acidity, the discussion of NaY adsorption capacity can be viewed in light of the higher capacity for NNIs found for the corresponding H-form sample, HY1 (with a similar Si/Al ratio). It is known that the substitution of H + in zeolite extra-framework positions with a metal cation, for instance, FeZSM-5, 34 has proved not to be a justified choice for pesticide glyphosate adsorption in comparison to zeolite H-forms. At first, it may seem that the influence of cations is dominant; however, regardless of the H-form of all other tested zeolites, the two ZSM-5 zeolites also showed minor adsorption capacities, so other parameters must be considered.…”

Section: Resultsmentioning

confidence: 99%

MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination

Milojević-Rakić

Popadić²,

Janošević

et al. 2022

Environ. Sci.: Processes Impacts

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Section: Resultsmentioning

confidence: 99%

MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination

Milojević-Rakić

Popadić²,

Janošević

et al. 2022

Environ. Sci.: Processes Impacts

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“…Conducting, semiconducting, and nonconducting polymers were prepared . For example, polyaniline-zeolite (PANI/ZSM-5 and PANI-FeZSM-5) composite-based adsorbents of efficient GLP adsorption capacity were prepared by oxidative polymerization. , Polydopamine (PDA) was used to synthesize BiVO 4 /PDA- g -C 3 N 4 photocatalyst sheets for exploiting dopamine self-polymerization, ultrasonic dispersion, and self-assembling. Under visible light irradiation, the BiVO 4 /PDAg-C 3 N 4 photocatalysts degraded GLP more actively than the control composites prepared without PD .…”

Section: Sensors and Separation Systems For Glp Determinationmentioning

confidence: 99%

Glyphosate Separating and Sensing for Precision Agriculture and Environmental Protection in the Era of Smart Materials

Mazuryk

Klepacka

Kutner

et al. 2023

Environ. Sci. Technol.

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The present article critically and comprehensively reviews the most recent reports on smart sensors for determining glyphosate (GLP), an active agent of GLP-based herbicides (GBHs) traditionally used in agriculture over the past decades. Commercialized in 1974, GBHs have now reached 350 million hectares of crops in over 140 countries with an annual turnover of 11 billion USD worldwide. However, rolling exploitation of GLP and GBHs in the last decades has led to environmental pollution, animal intoxication, bacterial resistance, and sustained occupational exposure of the herbicide of farm and companies' workers. Intoxication with these herbicides dysregulates the microbiomegut-brain axis, cholinergic neurotransmission, and endocrine system, causing paralytic ileus, hyperkalemia, oliguria, pulmonary edema, and cardiogenic shock. Precision agriculture, i.e., an (information technology)-enhanced approach to crop management, including a site-specific determination of agrochemicals, derives from the benefits of smart materials (SMs), data science, and nanosensors. Those typically feature fluorescent molecularly imprinted polymers or immunochemical aptamer artificial receptors integrated with electrochemical transducers. Fabricated as portable or wearable lab-on-chips, smartphones, and soft robotics and connected with SM-based devices that provide machine learning algorithms and online databases, they integrate, process, analyze, and interpret massive amounts of spatiotemporal data in a user-friendly and decision-making manner. Exploited for the ultrasensitive determination of toxins, including GLP, they will become practical tools in farmlands and point-of-care testing. Expectedly, smart sensors can be used for personalized diagnostics, real-time water, food, soil, and air quality monitoring, site-specific herbicide management, and crop control.

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“…Properties such as simple synthesis, low production cost, and high conductivity among others qualify PANI to be among the most crucial and well-studied conducting polymers [102]. The nature of PANI composite systems help in aiding the successful elimination of a wide range of toxic and ecotoxic substances [103][104][105].…”

Section: Zeolitesmentioning

confidence: 99%

Risk assessment and the adsorptive removal of some pesticides from synthetic wastewater: a review

Garba

Abdullahi

Haruna

et al. 2021

Beni-Suef Univ J Basic Appl Sci

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Background The need for environmental protection and remediation processes has been an increasing global concern. Pesticides are used as biological agents, disinfectants, antimicrobials, and also in a mixture of some chemical substances. Their modes of application are through selective dispensing and attenuation processes which act upon any pest that compete with the production, processing, and storage of foods and also in agricultural commodes. The pests might comprise weeds, insects, birds, fish, and microbes. Main body Pesticides are commonly found in water surface, landfill leachate, ground water, and wastewater as pollutant. An overview of recently studied adsorption processes for the pesticide elimination from polluted water has been reported in this study utilizing activated carbon, clay materials, biomass materials, metal organic frame work, graphene, and carbon-based materials as well as agricultural wastes as adsorbents. The risk assessment and cost analysis of adsorbents were also provided. Conclusion Evidences from literature recommend modified adsorbent and composite materials to have a prospective use in pesticide removal from wastewater. The adsorption data obtained fitted into different isotherm and kinetic models and also the thermodynamic aspect have been discussed. Graphical abstract

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Polyaniline/FeZSM-5 composites – Synthesis, characterization and their high catalytic activity for the oxidative degradation of herbicide glyphosate

Cited by 25 publications

References 61 publications

MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination

MFI, BEA and FAU zeolite scavenging role in neonicotinoids and radical species elimination

Glyphosate Separating and Sensing for Precision Agriculture and Environmental Protection in the Era of Smart Materials

Risk assessment and the adsorptive removal of some pesticides from synthetic wastewater: a review

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