Polyarenes II

doi:10.1007/978-3-319-07302-6

Cited by 5 publications

(1 citation statement)

References 106 publications

(329 reference statements)

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“…3 The successful synthesis of these non-benzenoid compounds has recently provided profound insights into the electronic properties of antiaromatic and/or open-shell systems. [4][5][6][7][8][9] For example, these antiaromatic compounds have demonstrated higher charge carrier mobility than their aromatic counterparts, 10 although the interpretation of these properties is still unclear. 11,12 Unfortunately, conventional wet synthesis of conjugated polymers containing nonbenzenoid compounds is difficult in the case of unstable nal compounds due to their inherent low solubility, high intrinsic reactivity and the occurrence of undesirable structural defects 13 that prevent complete control of the molecular structure.…”

Section: Introductionmentioning

confidence: 99%

On-surface synthesis of non-benzenoid conjugated polymers by selective atomic rearrangement of ethynylarenes

et al. 2023

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Section: Introductionmentioning

confidence: 99%

On-surface synthesis of non-benzenoid conjugated polymers by selective atomic rearrangement of ethynylarenes

et al. 2023

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Reactions of HDDA-Derived Benzynes with Perylenes: Rapid Construction of Polycyclic Aromatic Compounds

Xiao

Hoye

2016

Org. Lett.

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Benzynes produced by the thermal cycloisomerization of tetrayne substrates [i.e., by the hexadehydro-Diels–Alder (HDDA) reaction] react with perylenes to produce novel naphthoperylene derivatives. Cyclic voltammetry and absorption and emission properties of these compounds are described. DFT studies shed additional light on the dearomatization that accompanies the reaction as well as some of the spectroscopic behavior.

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A Synthetic Strategy for the Construction of Functionalized Triphenylene Frameworks via Palladium Catalyzed Intramolecular Annulation/Decyanogenative C–H Bond Alkenylation

et al. 2019

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The palladium catalyzed synthesis of 14-phenylbenzo[f]tetraphene-9-carbonitrile derivatives as core polycyclic aromatic hydrocarbons (PAHs) was achieved via an intramolecular annulation and decyanogenative C–H bond alkenylation strategy. A readily synthesized Knoevenagel condensation product of [1,1′-biphenyl]-2,2′-dicarbaldehyde with benzyl cyanide converted successfully into 14-phenylbenzo[f]tetraphene-9-carbonitrile derivatives in excellent yields up to 94%. The transformation involves an intramolecular cascade C–C bond formation along with a C–H bond cleavage sequence.

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Polyarenes II

Cited by 5 publications

References 106 publications

On-surface synthesis of non-benzenoid conjugated polymers by selective atomic rearrangement of ethynylarenes

On-surface synthesis of non-benzenoid conjugated polymers by selective atomic rearrangement of ethynylarenes

Reactions of HDDA-Derived Benzynes with Perylenes: Rapid Construction of Polycyclic Aromatic Compounds

A Synthetic Strategy for the Construction of Functionalized Triphenylene Frameworks via Palladium Catalyzed Intramolecular Annulation/Decyanogenative C–H Bond Alkenylation

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