Polydopamine-Based Polymer Layer for Enhanced Interfacial Properties of Hybrid Ceramic–Polymer Solid Electrolytes

Ferreira, Manuela; Schmidt, Robert; Xu, Fan; Ketabi, Sanaz; Cai, Mei; Zhu, Yingxi

doi:10.1021/acsaem.3c02350

Cited by 2 publications

(1 citation statement)

References 66 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Various polymer coatings have been applied based on Lewis acid–base interactions to improve the contact area between ceramics and polymers and increase the concentration of free Li ions at the interface, such as polyethylene carbonate (PEC), polydopamine (PDA), − poly-1,3-dioxolane (PDOL), and poly(methyl methacrylate) (PMMA) . Among them, PDA has been widely studied owing to its excellent binding properties and simple modification methods.…”

Section: Introductionmentioning

confidence: 99%

Diversifying Ion-Transport Pathways of Composite Solid Electrolytes for High-Performance Solid-State Lithium-Metal Batteries

Han,

Li,

Zhang

2024

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

The application of composite solid electrolytes (CSEs) in solid-state lithium-metal batteries is limited by the unsatisfactory ionic conductivity underpinned by the low concentration of free lithium ions. Herein, we propose an interface design strategy where an amine silane linker is employed as a coupling agent to graft the Li7La3Zr2O12 (LLZO) ceramic nanofibers to the poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) polymer matrix to enhance their interaction. The hydrogen bonding between amino-functionalized LLZO (NH2@LLZO) and PVDF-HFP not only effectively induces a uniform incorporation of high-content nanofibers (50 wt %) into the polymer matrix but also furnishes sufficient continuous surfaces to weaken the complexation between PVDF-HFP and Li-ion carriers. Additionally, introduction of the hydrogen bond and Lewis acid–base interplay strengthens the interfacial interactions between NH2@LLZO and lithium salts that release more free lithium ions for efficient interfacial transport. The impact of the linker’s structure on the dissociation capacity of lithium salts is systematically studied from the steric effect perspective, which affords insights into interface design. Conclusively, the composite solid electrolyte achieves a high ionic conductivity (5.8 × 10–4 S cm–1) by synergy of multiple transport channels at ceramic, polymer, and their interface, which effectively regulates the lithium deposition behavior in symmetric cells. The excellent compatibility of the electrolyte with both LiFePO4 and LiNi0.8Co0.1Mn0.1O2 cathodes also results in a long lifetime and a high rate capability for full cells.

show abstract

Section: Introductionmentioning

confidence: 99%

Diversifying Ion-Transport Pathways of Composite Solid Electrolytes for High-Performance Solid-State Lithium-Metal Batteries

Han,

Li,

Zhang

2024

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

show abstract

Tape-Casting Fabrication Techniques for Garnet-Based Membranes in Solid-State Lithium-Metal Batteries: A Comprehensive Review

Zhao,

Mo,

Mao

et al. 2024

ACS Appl. Mater. Interfaces

View full text Add to dashboard Cite

The growing demand for advanced solid-state lithium metal batteries has attracted considerable attention to the development of garnet-based membranes, known for their high ionic conductivity and superior electrochemical stability. Among the fabrication methods for garnet-based membranes, the tapecasting method is recognized as a mature and widely applied process, characterized by its simplicity, low cost, and suitability for large-scale production. In this review paper, we provide a comprehensive summary of this topic, emphasizing the intricate interplay among material properties, processing parameters, and membrane performance. We discuss key challenges in creating dense and porous garnet membranes, including controlling lithium volatilization, optimizing pore size, and maintaining high mechanical strength. We also evaluate emerging strategies for interface engineering and integration with other fabrication techniques, offering insights into scalability and environmental considerations of the tape-casting process. This review is a valuable resource for researchers seeking to advance solid-state lithium metal batteries through innovative tape-casting methods.

show abstract

Polydopamine-Based Polymer Layer for Enhanced Interfacial Properties of Hybrid Ceramic–Polymer Solid Electrolytes

Cited by 2 publications

References 66 publications

Diversifying Ion-Transport Pathways of Composite Solid Electrolytes for High-Performance Solid-State Lithium-Metal Batteries

Diversifying Ion-Transport Pathways of Composite Solid Electrolytes for High-Performance Solid-State Lithium-Metal Batteries

Tape-Casting Fabrication Techniques for Garnet-Based Membranes in Solid-State Lithium-Metal Batteries: A Comprehensive Review

Contact Info

Product

Resources

About