1960
DOI: 10.1002/pol.1960.1204815043
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Polyethylidene from diazoethane upon metal catalysts: Chromatographic analysis of evolved gases and mechanism of reaction

Abstract: It has already been shown that many pure metals, as evaporated metal films, are suitable catalysts in giving polyethylidene from the decomposition of diazoethane in ethereal solution, whilst other metals (for instance Ag and Pd), although decomposing diazoethane, do not give polymer. The composition of the gases evolved during the reaction, as obtained by gas chromatographic analyses, is different in the two cases: besides nitrogen the 2‐butenes represent the main fraction of the gases evolved when polymer for… Show more

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Cited by 9 publications
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