Polyfluorinated mercury thiolates. 199Hg NMR studies and the crystal structure of [Hg(SC6H4(CF3)-2)2]

Supramolecular aggregation featuring Hg⋯S secondary-bonding interactions in crystals of mercury(ii) species augmented by computational chemistry calculations

“…In 19 , 85 the mercury atom is coordinated within an approximately linear geometry by two pyridylthiolato-S atoms and the chain is propagated by glide symmetry. In 20 , 86 Fig. 5(a), the linear geometry is defined by two phenylthiolato-S atoms as is the case for 21 .…”