2009
DOI: 10.1039/b900141g
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Polyhedral oligomeric silsesquioxane nanocomposites exhibiting ultra-low dielectric constants through POSS orientation into lamellar structures

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Cited by 48 publications
(45 citation statements)
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“…In addition to the chain addition reaction discussed in the previous work [21], methacrylate groups are also capable to perform Michael addition reaction and DA reaction. This feature draws our attempt to extend the reaction scope of MMA-POSS and preparation of the corresponding MMA-POSS based hybrid materials.…”
Section: Introductionmentioning
confidence: 96%
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“…In addition to the chain addition reaction discussed in the previous work [21], methacrylate groups are also capable to perform Michael addition reaction and DA reaction. This feature draws our attempt to extend the reaction scope of MMA-POSS and preparation of the corresponding MMA-POSS based hybrid materials.…”
Section: Introductionmentioning
confidence: 96%
“…Multifunctional methacrylated-POSS (MMA-POSS) has been demonstrated to carry out self-crosslinking reaction through the polymerization of methacrylate groups [21]. In addition to the chain addition reaction discussed in the previous work [21], methacrylate groups are also capable to perform Michael addition reaction and DA reaction.…”
Section: Introductionmentioning
confidence: 97%
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“…For example, the ability of POSS-containing materials to form a passivation layer in highly oxidative environments shows great promise in a variety of applications, including lunar exploration and habitation missions [9][10][11]. Good thermal stability, re-workable characteristics and ultra-low dielectric constants of POSS nanocomposite films represents high potentials for uses in modern and future microelectronics [12]. However, the preparation of thin POSS-based films presents some technical difficulties related to wetting and adhesive properties of a given material, which are influenced by both surface chemistry and topography.…”
Section: Introductionmentioning
confidence: 98%
“…On the basis of the fact that caged type POSSs have internal space and good property of dielectric constants, they have been incorporated into polymer matrices to obtain low dielectric constant materials [14][15][16][17][18][19][20]. In the optoelectronic applications, POSSs have been employed to improve the thermal stability of photo resist [21][22][23][24] and light emitting diode (LED), the response speed of electrochromic materials [25][26][27], and luminescence efficiency.…”
Section: Introductionmentioning
confidence: 99%