2023
DOI: 10.1021/acsanm.3c00834
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Polymer-Grafted Graphene Oxide/Polybenzimidazole Nanocomposites for Efficient Proton-Conducting Membranes

Abstract: In this study, we have functionalized graphene oxide (GO) by growing polymer chains on its surface and then utilized the polymer-g-GO as a nanofiller with oxypolybenzimidazole (OPBI) to make a highly efficient nanocomposite-based proton exchange membrane (PEM). Three different monomers, namely, acrylamide (AAM), 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), and 3-sulfopropyl acrylate potassium salt (SPAK), were polymerized on the activated GO surface via surface-initiated reversible addition fragmentati… Show more

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Cited by 28 publications
(41 citation statements)
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“…The glass transition temperatures ( T g ) of the samples are obtained from the loss modulus ( E ″) and tan δ plots (Figure S12) and the corresponding values are summarized in Table S3 of the Supporting Information. Due to the formation of miscible blend membranes, loss modulus ( E ″) and tan δ plot exhibit only a single relaxation peak for m -PBI-P@MCOF composite MMMs, and the temperature associated with that peak is considered as the glass transition temperature ( T g ). The T g value of m -PBI is 320 °C (loss modulus plot) and 340 °C (tan δ plot), respectively. The incorporation of P@MCOF fillers results slight decrement in the T g values, and with the increase in the P@MCOF loading gradual decrement in T g value is observed (Table S3) which might be due to the polymer-COF interactions present in the composite membrane matrix.…”
Section: Resultsmentioning
confidence: 99%
“…The glass transition temperatures ( T g ) of the samples are obtained from the loss modulus ( E ″) and tan δ plots (Figure S12) and the corresponding values are summarized in Table S3 of the Supporting Information. Due to the formation of miscible blend membranes, loss modulus ( E ″) and tan δ plot exhibit only a single relaxation peak for m -PBI-P@MCOF composite MMMs, and the temperature associated with that peak is considered as the glass transition temperature ( T g ). The T g value of m -PBI is 320 °C (loss modulus plot) and 340 °C (tan δ plot), respectively. The incorporation of P@MCOF fillers results slight decrement in the T g values, and with the increase in the P@MCOF loading gradual decrement in T g value is observed (Table S3) which might be due to the polymer-COF interactions present in the composite membrane matrix.…”
Section: Resultsmentioning
confidence: 99%
“…The composite membranes comprising polymer/GO have gained much attention in recent years due to their high surface areas comprised of hydrophilic functionalities which help in the proton transport . However, the agglomeration of GO in the composite resulting from the incompatibility between the surface functionalities present on GO and the polymer can affect the membrane properties .…”
Section: Nonfluorinated Arylene Polymer Membranesmentioning
confidence: 99%
“…Functionalization of GO with a surface grafted polymer chain is an effective method to enhance the properties of the GO/polymer composite membrane. Das et al used this strategy to modify the surface of GO by growing polymer chains on its surface and prepared polymer- g -GO/OPBI based nanocomposite membranes by varying the loading of the nanofiller into the polymer . The prepared nanocomposite membranes showed enhancements in properties such as proton conductivity, tensile strength, and thermal stability.…”
Section: Nonfluorinated Arylene Polymer Membranesmentioning
confidence: 99%
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“…Syntheses of graphene oxide (GO), amine-modified GO (GO-EDA), and [3-benzylsulfanylthiocarbonylsufanyl-propionic acid] or BSPA RAFT agent, and the activation of the BSPA RAFT agent and its covalent attachment to the GO surface in order to synthesize GO-BSPA, are reported in detail in our earlier work. 39 We utilized identical batches of GO and RAFT-functionalized GO [GO−BSPA] for the development of PIL-g-GO materials in our current work. The synthesis of 3-butyl-1-vinylimidazolium iodide [VImBu][I] and 1butyl-2-methyl-1-(4-vinylbenzyl)imidazolium iodide [VBImBu][I] was performed following the literature−reported procedure, and characterization data are given in the Supporting Information (Figures S1 and S2).…”
Section: ■ Experimental Sectionmentioning
confidence: 99%