Material used as an electrical insulation has to combine many features, mainly dielectric, mechanical, and thermal parameters should be preserved. Appropriately selected polymer matrix and a suitable filler allow to obtain a multifunctional material for electrical devices. In the presented work, different types of commercial aluminosilicate fillers were used in order to obtain electrical insulation with enhanced properties in relation to reference silica‐epoxy resin composite. Thermal conductivity, mechanical parameters, dielectric properties and structure‐properties relationship were studied in order to examine the influence of size, amount and type of silanization of the filler. Composites filled with aluminosilicates exhibit much better mechanical properties as well as enhanced dielectric properties with 61% relative increase of thermal conductivity when they were compared with silica‐epoxy resin sample. The obtained results indicate that aluminosilicates are very attractive fillers for epoxy‐based composites used as an electrical insulation in power devices. POLYM. COMPOS., 40:3182–3188, 2019. © 2018 Society of Plastics Engineers