Polymer monoliths synthesized by radiation co-polymerization in solution

Beiler, Barbara; Sáfrány, Ágnes

doi:10.1016/j.radphyschem.2007.02.030

Cited by 10 publications

(10 citation statements)

References 7 publications

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“…2-Hydroxyethyl acrylate (HEA) is also a biocompatible monomer, which can be introduced into the monolith backbone in order to increase its biocompatibility. For example, increasing the HEA monomer content in the comonomer mixture (up to 18 vol%) in the preparation of the hydrophilic poly(HEAco-diethylene glycol dimethacrylate) monolith by radiation-induced polymerization [102,103], resulted in monoliths with increased hydrophilic character. However, further increase of HEA monomer content transformed the monolith into a soft gel.…”

Section: Poly(meth)acrylate-based Monolithsmentioning

confidence: 99%

Biocompatible polymeric monoliths for protein and peptide separations

Lee²

2009

J of Separation Science

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The concept of biocompatibility with reference to chromatographic stationary phases for separation of biomolecules (including proteins and peptides) is introduced. Biocompatible is a characteristic that indicates resistance to nonspecific adsorption of biomolecules and preservation of their structures and biochemical functions. Two types of biocompatible polymeric monoliths [i. e., polyacrylamide- and poly(meth)acrylate-based monoliths] used for protein and peptide separations are reviewed in detail, with emphasis on size exclusion, ion exchange, and hydrophobic interaction chromatographic modes. Biocompatible monoliths for enzyme reactors are also included. The two main synthetic approaches to produce biocompatible monoliths are summarized, i. e., surface modification of a monolith that is not inherently biocompatible and direct copolymerization of hydrophilic monomers to form a biocompatible monolith directly. Integration of polyethylene glycol into the poly(meth)acrylate monolith network is becoming popular for reduction of non-specific protein interactions.

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Section: Poly(meth)acrylate-based Monolithsmentioning

confidence: 99%

Biocompatible polymeric monoliths for protein and peptide separations

Lee²

2009

J of Separation Science

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“…In the latter case, tubes of glass or fused silica capillaries are used as molds that do not absorb UV radiation. Additionally, other methods including radiation under 60 Co γ-source [ 43 , 44 , 45 ] or by atom transfer radical polymerization [ 46 ] have been used in the synthesis of macroporous cross-linked organic polymeric monoliths. Tubes of different size and material such as stainless steel [ 3 , 37 , 38 ], poly(ether-ether-ketone) (PEEK) [ 47 ], glass [ 36 ] and silica capillaries [ 40 ] were also used as molds.…”

Section: Continuous Macroporous Rodsmentioning

confidence: 99%

Macroporous Monolithic Polymers: Preparation and Applications

2009

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In the last years, macroporous monolithic materials have been introduced as a new and useful generation of polymers used in different fields. These polymers may be prepared in a simple way from a homogenous mixture into a mold and contain large interconnected pores or channels allowing for high flow rates at moderate pressures. Due to their porous characteristics, they could be used in different processes, such as stationary phases for different types of chromatography, high-throughput bioreactors and in microfluidic chip applications. This review reports the contributions of several groups working in the preparation of different macroporous monoliths and their modification by immobilization of specific ligands on the products for specific purposes.

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“…In general, the materials processing methods with the aid of physical effects, chemical effects and biology effects between high-energy radiation (such as gamma ray and electron beam) and matter is called radiation processing. At present, although the radiation processing obtain the very good application in many fields of polymwric materials [1][2][3][4][5][6][7][8][9][10][11][12][13], while the parathion of polymer-based nanocomposites via radiation technology is still a new field of polymer radiation processing.…”

Section: Introductionmentioning

confidence: 99%

Radiation Processing of Polymer-based Nanomaterials

Zhou¹,

Cao²,

Liu³

et al. 2016

Proceedings of the 3rd International Conference on Material Engineering and Application (ICMEA 2016)

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In this paper, the preparation of polymeric nanocomposite based on carbon nanotubes or/and graphene by radiation techniques were reviewed. The preparation of polyhedral poligomeric sisesquioxane (POSS)-polymer and montmorillonite-polymer nanocomposite using radiation methods were discussed. And the preparation of nano-particles/polymer nanocomposite s and polymer-polymer Nanocomposites via irradiation were also introduced.

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Polymer monoliths synthesized by radiation co-polymerization in solution

Cited by 10 publications

References 7 publications

Biocompatible polymeric monoliths for protein and peptide separations

Biocompatible polymeric monoliths for protein and peptide separations

Macroporous Monolithic Polymers: Preparation and Applications

Radiation Processing of Polymer-based Nanomaterials

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