Polymer-Supported Haloarene Chromium Dicarbonyl Isonitrile Complexes:  A Study of Their Synthesis and Reactivity

Baldoli, Clara; Maiorana, Stefano; Licandro, Emanuela; Casiraghi, Laura; Zinzalla, Giovanna; Seneci, Pierfausto; Magistris, Elisabetta de; Paio, and Alfredo; Marchioro, Carla

doi:10.1021/cc0340123

Cited by 13 publications

(3 citation statements)

References 6 publications

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“…[14] Polymer-anchored arene-tricarbonylchromium(0) complexes 3-PS were employed as traceless linkers for performing metal-activated, aromatic nucleophilic substitution reactions on a solid support. [15] Fischer carbene complexes were prepared on a polymer support. Amination with benzylamine to give amino-carbene 4-PS and oxidative cleavage with I 2 /air releases the oxygenated amino-carbene ligand.…”

Section: Introductionmentioning

confidence: 99%

Solid‐Phase Synthesis of Transition‐Metal Complexes

Heinze

Beckmann

Hempel

2008

Chemistry A European J

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This overview highlights recent progress in the field of selective construction of linear, oligonuclear transition-metal complexes by using solid-phase synthesis procedures. Two general protocols have been identified: formation of coordinative bonds between metal centres and bridging ligands and formation of covalent bonds between preformed kinetically inert transition-metal-containing building blocks in the chain growth step. Currently available suitable building blocks for the second approach are based on ferrocene units, bis(terpyridine)-ruthenium(II) moieties or metal porphyrins.

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Section: Introductionmentioning

confidence: 99%

Solid‐Phase Synthesis of Transition‐Metal Complexes

Heinze

Beckmann

Hempel

2008

Chemistry A European J

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“…While many methods for carbon−carbon bond formation have been adapted for parallel synthesis both in solution and on solid phase, the majority of these are palladium-catalyzed reactions. Carbocations stabilized by metal carbonyl complexes can be used both for carbon−carbon and carbon−heteroatom formation, yet there are few examples of the application of such methods in parallel synthesis although iron carbonyl-mediated S N Ar reactions on solid phase have been adapted for combinatorial purposes …”

Section: Introductionmentioning

confidence: 99%

Iron Carbonyl-Mediated Parallel Solution-Phase Synthesis of Cyclohexadienoic Acid Amides

et al. 2004

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Iron carbonyl-stabilized cations have been employed to develop methodology for carbon-carbon and carbon-heteroatom formation suitable for the preparation of combinatorial libraries. Different nucleophiles were added to tricarbonyl(cyclohexa-1,3-dienylcarboxylic acid 4-nitro-phenyl ester)iron hexafluorophosphate. Aminolysis, followed by decomplexation, yielded substituted cyclohexadienyl amides of high purity. Carbon, oxygen, and sulfur nucleophiles gave good results, while amine nucleophiles gave products of somewhat lower purity.

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“…All entries are referenced by the first author's last name to facilitate reference cross-checking. Some 468 total entries are captured in the tables. − <...…”

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confidence: 99%

Comprehensive Survey of Combinatorial Library Synthesis: 2003

Dolle

2004

J. Comb. Chem.

135

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An exhaustive compilation of biologically active libraries covering the years 1992-1997 was presented in a previous review [1a]. In that review, libraries were divided among 4 major categories, including those active against proteases, non-proteolytic enzymes, Gprotein coupled receptors, and non-G-protein coupled receptors. A generic structure for each library was provided as well as the structure of the most active member. The number of biologically active libraries reported in the literature during this time period (86 total) represents <25% of the total number of published library constructs. Disclosure of library synthesis without accompanying screening data is a more common occurrence. Because these types of libraries are equally important to the practicing combinatorial chemist, it was thought that a comprehensive listing of such libraries spanning the years 1992-1997 would be a useful supplement to the previous review [1a,b].Library constructs [2-248] listed herein are relegated to one of five tables. Table 1 is entitled 'Scaffold derivatization' and includes all constructs in which a multi-functional scaffold is modified in some fashion to create a library. An example of a construct found in Table 1 would be the sequential addition of three nucleophiles to trichloropyrimidine. Table 2, entitled 'Acyclic synthesis', lists all linear constructs such as those derived from multi-component Ugi condensations.

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Polymer-Supported Haloarene Chromium Dicarbonyl Isonitrile Complexes: A Study of Their Synthesis and Reactivity

Cited by 13 publications

References 6 publications

Solid‐Phase Synthesis of Transition‐Metal Complexes

Solid‐Phase Synthesis of Transition‐Metal Complexes

Iron Carbonyl-Mediated Parallel Solution-Phase Synthesis of Cyclohexadienoic Acid Amides

Comprehensive Survey of Combinatorial Library Synthesis: 2003

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