1981
DOI: 10.1016/0014-3057(81)90040-9
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Polymerization by alkaline earth metal compounds—I. Studies on the polymerization of methylmethacrylate by triphenylmethyl metal derivatives and related compounds of calcium, strontium and barium

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Cited by 21 publications
(3 citation statements)
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“…Heavy Grignard reagents were first reported by Beckmann et al, 1 although other investigators were unable to verify the results. Over the years, several others have attempted the preparation of these elusive compounds, 40,41,63,93,94 resulting in widely contradictory reports on their preparation and reactivity. 95 Despite these difficulties, a few early investigators compiled compelling evidence for the existence of heavy Grignard reagents.…”
Section: Grignard Reactions (Vi)mentioning
confidence: 99%
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“…Heavy Grignard reagents were first reported by Beckmann et al, 1 although other investigators were unable to verify the results. Over the years, several others have attempted the preparation of these elusive compounds, 40,41,63,93,94 resulting in widely contradictory reports on their preparation and reactivity. 95 Despite these difficulties, a few early investigators compiled compelling evidence for the existence of heavy Grignard reagents.…”
Section: Grignard Reactions (Vi)mentioning
confidence: 99%
“…Subsequent investigators were able to reproduce these results and extend the work to include (Ph 3 C)MX (M = Ca, Sr, Ba; X = Cl, Br). 40,41 Finally, Markies et al reported Ph 2 Ca, but reported no physical data. 93 The compound was obtained at À20 1C from a THF solution.…”
Section: Grignard Reactions (Vi)mentioning
confidence: 99%
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