1993
DOI: 10.1080/00914039308048358
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Polymerization by Phase Transfer Catalysis. 16.aSynthesis of Polyestercarbonates and Polyesterthiocarbonates

Abstract: Polyestercarbonates and polyesterthiocarbonates were synthesized from the diphenol-esters 4-hydroxyphenyl-4-hydroxybenzoate and 3-hydroxyphenyl-4-hydroxybenzoate and phosgene and thiophosgene respectively, under phase transfer catalysis conditions. The behaviour of the catalysts was evaluated by the yields and the inherent viscosities. Only the polyesterthiocarbonate derived from 3-hydroxyphenyl-4-hydroxybenzoate was soluble in the reaction media, being benzyltriethylammonium chloride (TE-BAC) an effective cat… Show more

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Cited by 10 publications
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