Polymerization of adsorbed monolayers. II. Thermal degradation of the inserted polymer

Blumstein, A.

doi:10.1002/pol.1965.100030721

Cited by 198 publications

(175 citation statements)

References 6 publications

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“…The improved thermal stability of the PMMA/ montmorillonite PNCs was first reported by Blumstein in 1965 [225]. Higher thermal stability and improved flammability performance make them suitable for hightemperature applications.…”

Section: Thermal Stabilitymentioning

confidence: 98%

A review on the role of interface in mechanical, thermal, and electrical properties of polymer composites

Kashfipour

Mehra

Zhu

2018

Adv Compos Hybrid Mater

176

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Composite materials and especially polymer composites are widely used in daily life and different industries due to their vastly different properties and design flexibility. It is known that the properties of the composites are strongly related to the properties of its constituents. However, it has been reported in many studies, experimentally and by simulations, that the characteristics of the composites do not follow the rule of mixing. It means that in addition to properties of the constituents, there are other parameters affecting the final physicochemical properties of composites. The interfacial interactions between fillers and host is one of the factors which can strongly affect the properties of the composite. In this review, we summarized the type of interactions between the constituents, their improvement techniques, interaction measurement methods, and the effects of interfacial interactions on thermal, mechanical, and electrical properties of composites.

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Section: Thermal Stabilitymentioning

confidence: 98%

A review on the role of interface in mechanical, thermal, and electrical properties of polymer composites

Kashfipour

Mehra

Zhu

2018

Adv Compos Hybrid Mater

176

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“…Thermogravimetric analysis (TGA) was used for characterizing the thermal stability of the TCE polymers, PVCi polymers and polymer blends. Weight loss due to thermal degradation is an irreversible process, which is highly related to oxidation through the interaction between the molecular bonds of a polymer and oxygen molecules [45][46][47] . Besides oxidation, polymers can be thermally degraded by random chain scission, side-group elimination and so on [48][49] .…”

Section: Effects Of Addition Of Polymers To the Thermal And Mechanicamentioning

confidence: 99%

Early damage detection in epoxy matrix using cyclobutane-based polymers

Zou

Liu

Shan

et al. 2014

Smart Mater. Struct.

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Identification of early damage in polymer composites is of great importance. We have incorporated cyclobutane-containing crosslinked polymers into an epoxy matrix, studied the effect on thermal and mechanical properties and more importantly, demonstrated early damage detection through mechanically induced fluorescence generation. Two cinnamate derivatives, 1,1,1-tris(cinnamoyloxymethyl) ethane (TCE) and poly(vinyl cinnamate) (PVCi), were photoirradiated to produce cyclobutane-containing polymer, respectively. The effects on the thermal properties and mechanical properties with the addition of cyclobutane-containing polymer into epoxy matrix were investigated. The emergence of cracks was detected by fluorescence at a strain level right beyond the yield point of the polymer blends and the fluorescence intensified with accumulation of strain. Overall, the results show that the damages can be detected through fluorescence generation along the crack propagation.

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“…Indeed, the use of nanoparticules in polymer is an effective way to improve some properties such as mechanical 1,2,3,4 , barrier 5, 6 , thermal 7 and in some cases fire 8, 9 properties.…”

Section: Introductionmentioning

confidence: 99%

Crossed characterisation of polymer-layered silicate (PLS) nanocomposite morphology: TEM, X-ray diffraction, rheology and solid-state nuclear magnetic resonance measurements

Samyn

Bourbigot

Jama

et al. 2008

European Polymer Journal

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ArticleCrossed characterisation of polymer layered silicate (PLS) nanocomposite morphology: TEM, X ray diffraction, rheology and solid state nuclear magnetic resonance measurements SAMYN, F, BOURBIGOT, S, JAMA, C, BELLAYER, S, NAZARE, S, Hull, T Richard, CASTROVINCI, A, FINA, A and CAMINO, G Available at http://clok.uclan.ac.uk/1134/ SAMYN, F, BOURBIGOT, S, JAMA, C, BELLAYER, S, NAZARE, S, Hull, T Richard, CASTROVINCI, A, FINA, A and CAMINO, G (2008) Abstract:As the nanocomposite properties dramatically depend on the dispersion state of the filler in the matrix, it is essential to develop technical methods to characterise the nanodispersion both qualitatively and quantitatively. In this study, complete characterisations of the nanodispersion of organomodified clays in polyamide 6, polypropylene and poly(butylene terephtalate) are presented and discussed using different analytical tools including X-ray diffraction and transmission electron spectroscopy and more original and quantitative measurements like rheology and solid state NMR measurements.

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Polymerization of adsorbed monolayers. II. Thermal degradation of the inserted polymer

Cited by 198 publications

References 6 publications

A review on the role of interface in mechanical, thermal, and electrical properties of polymer composites

A review on the role of interface in mechanical, thermal, and electrical properties of polymer composites

Early damage detection in epoxy matrix using cyclobutane-based polymers

Crossed characterisation of polymer-layered silicate (PLS) nanocomposite morphology: TEM, X-ray diffraction, rheology and solid-state nuclear magnetic resonance measurements

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