Epoxy/TiO 2 composites were prepared by solution mixture method, in which epoxy resin and nano-TiO 2 liquid were mixed in the presence of methyl isobutylketone. According to the experimental results, hydrogen bonds can be formed by mixing TiO 2 particles and epoxy resin. The SEM analysis suggests that TiO 2 particles are uniformly distributed within the material, while some silver streaks occur at the surface of materials. Besides, thermo-resistance and mechanical property of materials are found to improve with the addition of TiO 2 , but degrades if the nano-TiO 2 is the excess of 3%. Furthermore, these properties can be improved with the increasing concentration of methyl isobutylketone.