Two anthryl-functionalized cyanide-bridged {Fe4Co4} cube complexes, [(pzTp)Fe(CN)3Co(TpEtOAn)]4[OTf]4·8MeCN·7Et2O (1) and [NEt4]3[(pzTp)Fe(CN)3Co(TpEtOAn)]4[OTf]7·5MeCN·2Et2O (2) (pzTp– = tetrapyrazolylborate, TpEtOAn = 2,2,2-tris-(pyrazol-1-yl)ethoxy(9-methyl-anthracene), were synthesized and characterized. The crystallographic study revealed that the {Fe4Co4} cubes are...