Polyoxometalate-based materials against environmental pollutants: A review

Aramesh, Nahal; Reza Bagheri, Ahmad; Zhang, Zheng; Yadollahi, Bahram; Kee Lee, Hian

doi:10.1016/j.ccr.2024.215767

Coordination Chemistry Reviews

2024

DOI: 10.1016/j.ccr.2024.215767

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Polyoxometalate-based materials against environmental pollutants: A review

Nahal Aramesh,

Ahmad Reza Bagheri,

Zheng Zhang

et al.

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Cited by 19 publications

References 315 publications

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Ultra‐thin C/Si Shell Pieces as Amphiphilic Janus Materials for Efficient Oxidation Desulfurization

Zhang,

Liu,

Jin

et al. 2024

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Constructing favorable morphology is considered to be an effective strategy to enhance the amphiphilic performance of materials. The directional alignment of ultra‐thin lamellar materials significantly facilitates utilization of active sites at the bi‐phase interface. Herein, an ultra‐thin amphiphilic C/Si shell pieces Janus material (d = 10.4 nm) prepared by graphene oxide and SiO2 is reported. The outer SiO2 layer is associated with hydrophilicity, while the inner C layer exhibits hydrophobicity. A Pickering emulsion interface catalyst for fuel oil oxidative desulfurization is constructed by impregnating an amino‐modified C/Si Janus material with keggin‐type HPW. The results demonstrate that amphiphilic catalyst with an ultra‐thin C/Si shell pieces exhibits superior performance in terms of emulsification rate (100%) and desulfurization rate (99.62%) in the O/W emulsion formed by n‐octane/acetonitrile. The catalyst demonstrates the advantages of easy recovery and regeneration, maintains a higher activity after oxidative desulfurization (ODS) process, and has higher industrial application value.

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Ultra‐thin C/Si Shell Pieces as Amphiphilic Janus Materials for Efficient Oxidation Desulfurization

Zhang,

Liu,

Jin

et al. 2024

Small

View full text Add to dashboard Cite

show abstract

Polyoxometalates containing aluminum atoms

Cui,

Fang,

Zhang

2024

Chinese Chemical Letters

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Versatile POMOF-based materials: Synthesis, mechanism, topology and catalytic applications

Sun,

Wang,

Kozhevnikov

2025

Coordination Chemistry Reviews

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Polyoxometalate-based materials against environmental pollutants: A review

Cited by 19 publications

References 315 publications

Ultra‐thin C/Si Shell Pieces as Amphiphilic Janus Materials for Efficient Oxidation Desulfurization

Ultra‐thin C/Si Shell Pieces as Amphiphilic Janus Materials for Efficient Oxidation Desulfurization

Polyoxometalates containing aluminum atoms

Versatile POMOF-based materials: Synthesis, mechanism, topology and catalytic applications

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