“…A Keggin-type polyoxometalate (PMo 12 ) was first reported to be used as the anode material of LIBs in 2012, and it was found that each PMo 12 molecule reversibly transfers 24 electrons during the lithiation and delithiation processes . From then on, some smaller POMs, including PMo 12 , − PMo 10 V 2 , − PW 12 , , SiW 12 , Co 8 W 12 , and so on, which are combined with functional support materials, such as MXene, − organic linkers, , MOFs, − CNTs, , and GO, , were mainly reported for energy storage.…”