Polyquinolines: A class of rigid‐chain polymers

Park

J of Applied Polymer Sci

et al. 1992

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Synthesis and photoelectrical properties of poly[2,6‐(p‐phenoxy)‐4‐phenylquinoline]

Park

J of Applied Polymer Sci

et al. 1992

Israel Journal of Chemistry

Chemistry of Organic Polyheterocyclic Conductors

Wudl

1986

The synthesis and some properties of polymeric heterocycles as well as the latest results in the area of soluble conducting polymers are reviewed. Polyheterocycles with long chain substituents exhibit unusual properties in solution while retaining a relatively high conductivity in the solid state. All known methods for the preparation of conducting polymers are presented and their merits discussed. Among the insoluble polymers, the electrochemical methods are still the best because they afford films on a large variety of substrates.

Macro Chemistry & Physics

Synthesis and characterization of new polyquinolines having terdendate N‐N‐N or N‐C‐N binding sites in the main backbone

Mamo¹,

Stefio²

1997

By reacting the monomer 4,4'-diamino-3,3'-bis@-methoxybenzoyl)diphenyl sulfide with 4,4'-diacetyldiphenyI sulfide and alternatively, with 2,6-diacetylpyridine or 1.3-diacetylbenzene in a m-cresolldi-m-cresyl phosphate medium, six new polyquinolines having terdendate N-N-N or N-C-N binding sites in the main backbone were obtained. The lower is the number of binding sites present in the main backbone the higher is the degree of rigidity of the resulting polymers. 'H nuclear magnetic resonance (NMR) and infrared (IR) spectral data support the structure of the synthesized polymers. Thermal analysis data confirm the good thermal stability of this class of polymers. Two examples of macromolecular complexes with Os++ are also reported. Y = N Terdentate Ligand (bmpqpy) Y =CH Cyclometallating Ligand (bmpqb-H)