Polysulfone with glycopolymer for development of antifouling ultrafiltration membranes

Multiwall carbon nanotubes (MWCNTs) are often used to modify polymer membranes as additives, however, MWCNTs are easy to agglomerate and entangle in polymer matrix due to their own strong van der Waals force. MWCNTs were doubly modified by bonding octadecylamine (ODA) and SiO2 through the respective amidation and esterification reactions to prepare SiO2-MWCNT-ODA nanocomposites. The amino groups on ODA were amidated with the carboxyl groups on MWCNT-COOH. Then the hydroxyl groups on SiO2 were bonded to MWCNT-COOH through esterification to obtain SiO2-MWCNT-ODA nanocomposites. PES/SiO2-MWCNT-ODA composite ultrafiltration (UF) membrane was prepared by non-solvent induced phase separation (NIPS) method. SiO2-MWCNT-ODA nanocomposites and PES/SiO2-MWCNT-ODA membrane were characterized by FTIR, XRD, TGA, and SEM, etc. The results showed that PES/SiO2-MWCNT-ODA membrane had significantly improved permeability, rejection, and antifouling properties for comparison with PES membrane. The pure water flux of PES/Nano.2-0.5 reached 212.5 L m−2 h−1, which was approximately 2.6 times than that of PES membrane, and the rejection of BSA protein for composite membrane was as high as 94.2%. PES/SiO2-MWCNT-ODA composite membrane had excellent antifouling performance and the flux recovery rate (FRR) of PES/Nano.2-0.5 membrane could still maintain at higher value of 84.82% after two cycles in the antifouling test.

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A Pilot-Scale Treatment of Steel Plant Wastewater by PVDF Hollow Fiber Ultrafiltration Membrane with Low Packing Density

Zhang

Yuan

Bai

et al. 2022

Separations

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The treatment of wastewater from the iron and steel industry is difficult due to its complex and changeable characteristics. This paper introduces the application of polyvinylidene fluoride (PVDF)-pressurized ultrafiltration membrane with low packing density that produced via thermally induced phase separation (TIPS) in wastewater of iron and steel industry, to study the effects of packing density of ultrafiltration membrane modules as well as the membrane performance under different operation conditions, in order to provide guidance for the subsequent development of other ultrafiltration applications in wastewater of iron and steel. The results show a significant positive effect of smaller packing density on the transmembrane pressure difference (TMP) reducing and higher permeability. Under 30 min filtration cycle and 65 L m−2 h−1 (LMH) operation flux, the permeability can be stabilized to 200 L/(m2·h)/0.1 MPa, which is two times higher than that of the membrane module with 0.3 m2/m3 higher packing density under the same condition. It is obvious that compared with enhanced flux maintenance (EFM), chemically enhanced backwash (CEB) is a more effective cleaning method for iron and steel wastewater, which maintains TMP (30 kPa) without any significant increase under the premise of ensuring the high-flux (65 LMH) operation. The results also suggest reasonable parameters based on the test water quality, which include the filtration cycle and operation flux. The scanning electron microscopy (SEM) analysis and the turbidity of the permeate show that the ultrafiltration membrane has good intercept ability and high anti-pollution performance.

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Polysulfone with glycopolymer for development of antifouling ultrafiltration membranes

Cited by 3 publications

References 55 publications

Amine-functionalized metal organic framework@graphene oxide as filler in PAEK-containing carboxyl group membrane for ultrafiltration with ultra-high permeability and strong fouling resistance

Amine-functionalized metal organic framework@graphene oxide as filler in PAEK-containing carboxyl group membrane for ultrafiltration with ultra-high permeability and strong fouling resistance

Doubly modified MWCNTs embedded in polyethersulfone (PES) ultrafiltration membrane and its anti-fouling performance

A Pilot-Scale Treatment of Steel Plant Wastewater by PVDF Hollow Fiber Ultrafiltration Membrane with Low Packing Density

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