Polyvalent iodine in organic chemistry: Recent developments, 2002–2005

Abstract

In the last three years, great strides were achieved in the field of organic chemistry of polyvalent iodine compounds. This paper includes the published works on this field from 2002-2005 (Zhdankin, V. V.; Stang, P.

Polyvalent perfluoroorgano- and selected polyfluoroorgano-halogen(III and V) compounds

“…(9b)) [31]. Primary perfluoroalkyl iodides react with ClOS(O) 2 [33]. In a similar manner the oxidative addition of OCl groups was performed when 2 equiv.…”

“…This approach was originally developed in 1959 by Schmeißer and Scharf [3] for CF 3 IF 2 and later applied and modified for other perfluoroalkyl, perfluoroalkenyl, and perfluoroaryl iodides R F I þ F 2 ðdilutedÞ À ! CCl 3 F;À78 C R F IF 2 (1)…”

One-pot process in phosphonium-iodonium ylides: nucleophilic substitution and the Wittig reaction

“…9 The yield was 80%. 1 13 Reaction of ylide 1 with trimethylsilyl iodide. Synthesis of α α α α α halogen substituted acrylic acid esters 3c,f,i,n (general proce dure).…”

“…31 P NMR (CDCl 3 ), δ: 28.77. 1 X ray diffraction study. X ray diffraction data were collected from transparent crystals of compound 4.…”

“…The yield was 60%. Z isomer (55%) 1. H NMR (CDCl 3 ), δ: 1.40 (t, 3 H, Me, J = 7.0 Hz); 4.36 (q, 2 H, CH 2 , J = 7.0 Hz); 7.58 and 7.67 (both d, 2 H each, H arom., 3 J H,H = 8.6 Hz, 3 J H,H = 8.5 Hz); 8.21 (s, 1 H, CH).…”