Constructing potential anodes for sodium-ion batteries (SIBs) with a wide temperature property has captured enormous interests in recent years. Fe 1−x S, a zero-band gap material confirmed by density states calculation, is an ideal electrode for fast energy storage on account of its low cost and high theoretical capacity. Herein, Fe 1−x S nanosheet wrapped by nitrogen-doped carbon (Fe 1−x S@NC) is engineered through a post-sulfidation strategy using Fe-based metal-organic framework (Fe-MOF) as the precursor. The obtained Fe 1−x S@NC agaric-like structure can well shorten the charge diffusion pathway, and significantly enhance the ionic/electronic conductivities and the reaction kinetics. As expected, the Fe 1−x S@NC electrode, as a prospective SIB anode, delivers a desirable capacity up to 510.2 mA h g −1 at a high rate of 8000 mA g −1 . Additionally, even operated at low temperatures of 0 and −25°C, high reversible capacities of 387.1 and 223.4 mA h g −1 can still be obtained at 2000 mA g −1 , respectively, indicating its huge potential use at harsh temperatures. More noticeably, the full battery made by the Fe 1−x S@NC anode and Na 3 V 2 (PO 4 ) 2 O 2 F cathode achieves a remarkable rate capacity (186.8 mA h g −1 at 2000 mA g −1 ) and an impressive cycle performance (183.6 mA h g −1 after 100 cycles at 700 mA g −1 ) between 0.3 and 3.8 V. Such excellent electrochemical performance is mainly contributed by its pseudocapacitive-dominated behavior, which brings fast electrode kinetics and robust structural stability to the whole electrode.