A model of essentially transient ionization of plasma is suggested to explain some features in observed spectra of solar flares, which cannot be understood if stationary conditions are assumed.In the recent papers of Doschek et al. (1979), Feldman et al. (1980), and Doschek et al. (1980 newly observed high-resolution X-ray spectra of solar flares were reported. It was pointed out that relative intensities of the resonance lines and satellites belonging to the He-like and H-like iron and calcium ions showed a non-steady-state character of ionization distribution in terms of an ionization temperature Tz and an electron temperature Te as introduced by Gabriel (1972). Te is determined from the intensity ratio of a dielectronic satellite (DS) to the resonance line (RL) of a particular ionization stage, and Tz is derived from the intensity ratio of an inner-shell excited satellite (IS) to RL and/or RL(Z) to RL(Z + 1) ratio of two subsequent ionization stages. Two essential points could not be explained satisfactorily in the spectra mentioned: (i) The spectra look like as if they originated from 'underionized' plasma (transient ionizing coriditions, Tz < Te) during the whole time history of a flare including the decay phase; (ii) the value of T, derived from the DS/RL ratio for the H-like ions Ca xx (the ionization energy IP = 5.3 keV) appears to be higher than that for the He-like ions Fe xxv with higher IP = 8.5 keV. E.g., at 18h09m24 ~ UT Te(Ca xx) = 30 • 106 K and Te(Fe xxv) = 22 • 106 K (see Table 1 in Doschek et al., 1979).The underionized conditions are observed also in most of laboratory plasma sources: vacuum sparks, laser-produced plasmas, tokamaks (see e.g. Kononov, 1978, Bitter et al., 1979. This effect may be of 'computational' origin: Atomic constants of highly ionized atoms which are used in interpretations of spectra could be calculated with some uncertainties. Until now, however, all the theoretical methods give rather consistent values for cross-sections and atomic transition probabilities, which always confirm the T~ > Tz trend (Bhalla et al., 1975;Vainstein et al., 1980). Moreover, in all the observations of very highly ionized atoms spectra, such as Fe xxv-xxvI, one can see that the product of the electron density Ne and the life-time of plasma r is comparable to the reCiprocal of the ionization rate of relevant ions. Hence, the transient character of ionization should be taken into account. The transient ionization approach is known to be applied to solar flares (see e.g. Mewe and Schrijver, 1980;Shapiro and Moore, 1977). Alternative attempts to bring Te and T~ into the ionization equilibrium consistency were made by Doschek et al. (1981). They account for higher level contributions to the Solar Physics 77 (1982) 177-181. 0038-0938/82/0771-0177 $00.75. Copyright 0 1982 by D. Reidel Publishing Co.,