The technology of CO2 geological storage and CH4 intensive mining (CO2-ECBM) in coal seams integrates greenhouse gas emission reduction and new fossil energy development and has great development prospects. The CO2 injection, CO2 sequestration mechanism and storage capacity, and CH4 stimulation effect constitute the core content of the effectiveness of CO2-ECBM, among which CO2 injection is the most critical. Traditional seepage analysis methods often struggle to tackle flow-related issues influenced by microscale effects and intricate channels. This paper highlights the advantages of employing lattice Boltzmann (LBM) numerical simulations to study CO2 seepage behaviors when teaching a Rock Mass Seepage Mechanics Course. This course primarily covers topics such as the pore structure of rock, unstable liquid seepage, gas seepage theory and related subjects. Its goal is to provide students with a solid theoretical foundation to address the complexities of fluid seepage in pours media encountered in practical scenarios. A novel LBM-based methodology was employed to estimate the CO2 seepage capacity by incorporating the effects of different concentrations of [Bmin]Cl solution (0 wt%, 1 wt%, 3 wt%, and 5 wt%). The CO2 velocity distribution cloud map of each coal sample was simulated; the average velocity distribution curve of each coal sample was obtained; and the velocity profile of the seepage channel of each coal sample was described. This study can provide theoretical guidance for the technology of CO2 geological storage and CH4 intensive mining in coal seams.