In the semiconductor industry, economical high-end interposer
technologies
with high thermal conductivity are in high demand. The recently reported
anodic aluminum oxide (AAO) template has limitations of low mechanical
strength and thermal conductivity due to the amorphous phase. In addition,
AAO has microthickness and nanopores, and it is easy to break. In
this study, the AAO template does not develop a microcrack at high
temperature by controlling the pores on the front and back side of
the same pore of the AAO, as concluded in the COMSOL simulation. The
nonmicrocrack alpha-AAO template is mechanically robust with high
thermal conductivity owing to thermal stress minimization and phase
transformation (anodizing temperature and annealing treatment). In
addition, anionic contamination components present on the surface
of the alpha-AAO pores were removed by increasing the temperature,
and the properties were investigated. The hardness and thermal conductivity
of the alpha-AAO template (8.98 GPa and 13.7 W/(m·K)) were 3.3
and 6.7 times higher than those of bare-AAO (2.74 GPa and 2.08 W/(m·K)),
respectively. Especially, the superior thermal conductivity of alpha-AAO
was confirmed by a thermal imaging camera (TIC). The alpha-AAO template
with enhanced hardness and thermal conductivity can potentially be
used in various applications, such as semiconductor interposer materials
and 6G wireless communication components.