Porous carbon derived via KOH activation of a hypercrosslinked porous organic polymer for efficient CO2, CH4, H2 adsorptions and high CO2/N2 selectivity

Modak, Arindam; Bhaumik, Asim

doi:10.1016/j.jssc.2015.09.022

Cited by 90 publications

(37 citation statements)

References 51 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Unlike carbonization of MOFs, [181] which resulted metal doped carbons with relatively smaller surface area than the parent MOFs, carbonization of amorphous POPs under inert atmosphere resulted largely enhanced BET surface areas (2000 m 2 g À1 or more) porous carbons. [182] Microporous carbons prepared via KOH activation and carbonization of POPs showed very storage capacities for CO 2 , CH 4 , H 2 etc. together with very high selectivity for CO 2 /N 2 and thus have huge future potential to mitigate the challenge of greenhouse gases in the universe.…”

Section: Future Perspectivesmentioning

confidence: 99%

“…Another important area is designing hierarchically porous carbon materials, which are very demanding in the context of energy and environmental research. Unlike carbonization of MOFs, which resulted metal doped carbons with relatively smaller surface area than the parent MOFs, carbonization of amorphous POPs under inert atmosphere resulted largely enhanced BET surface areas (2000 m 2 g −1 or more) porous carbons . Microporous carbons prepared via KOH activation and carbonization of POPs showed very storage capacities for CO 2 , CH 4 , H 2 etc.…”

Section: Future Perspectivesmentioning

confidence: 99%

See 1 more Smart Citation

Porous Organic Polymers for CO₂ Storage and Conversion Reactions

2018

Self Cite

View full text Add to dashboard Cite

To overcome the challenges of global warming and environmental pollution it is mandatory to reduce the concentration of atmospheric carbon dioxide (CO2), which is largely accumulated in air through the combustion of fossil fuels. Thus, sequestration of CO2 through physisorption on solid adsorbents and their successful conversion into value added fine chemicals are the major priority areas of research today. Innovation of efficient solid CO2‐philic adsorbents together with their high mechanical/chemical stability and regeneration efficiency are the most challenging objectives to achieve this goal. In this context, porous organic polymers (POPs) owing to their high specific surface area, chemical stability, nanoscale porosity and structural diversity have huge potential to play as selective CO2 adsorbent. POPs synthesized through large varieties of reactive monomers via simple and convenient chemical routes can be the ideal adsorbents for the CO2 storage and fixation reactions. A wide range of POPs can be synthesized from different multidentate amines, aldehydes, carboxylic acids or triazine monomers through the polycondensation reactions or solid state condensation reactions. Ease of synthesis, uniform pore width together with high surface area and surface basic sites (nitrogen and other heteroelements) play crucial role in the CO2 absorption and conversion reactions. This review provides a concise account in designing POPs and their application in CO2 adsorption and fixation into reactive organic molecules for the synthesis of fuels and value added fine chemicals.

show abstract

Section: Future Perspectivesmentioning

confidence: 99%

Section: Future Perspectivesmentioning

confidence: 99%

Porous Organic Polymers for CO₂ Storage and Conversion Reactions

2018

Self Cite

View full text Add to dashboard Cite

show abstract

“…On the other hand, porous carbons are also prepared through a facile one step carbonization from porous polymers. Recently, Modak et al have prepared microporous carbon (K-COP-M) having extremely high surface area of 2186 m 2 g −1 and contains micropore [82]. K-COP-M has been produced by KOH activation of COP-M polymer in an inert condition and at very high temperature (600-700°C).…”

Section: Nanoporous Carbon Compositementioning

confidence: 99%

Advances in Porous Adsorbents for CO2 Capture and Storage

Modak¹,

Jana²

2018

Carbon Dioxide Chemistry, Capture and Oil Recovery

Self Cite

View full text Add to dashboard Cite

The steady increase of anthropogenic CO 2 in ambient air, owing to the fossil fuel, power plants, chemical processing and deforestation caused by the usage of land, is a key challenge in the ongoing effort to diminish the effect of greenhouse gases on global climate change by developing efficient techniques for CO 2 capture. Global warming as a consequence of high CO 2 level in the atmosphere is considered as one of the major long lasting problems in the twenty-first century. Concern over these major issues with regard to severe climate change and ocean acidification motivated us to develop the technologies that capture the evolved CO 2 from entering into the carbon cycle. Therefore, CO 2 capture and storage technology is attracting increasing interest in order to reduce carbon level in the atmosphere which in turn mitigates global climate issues. In this regard, highly efficient adsorbents e.g.; zeolites, alkali metal oxides, activated carbon, porous silica show considerable progress in post combustion CO 2 capture. Recently, metal-organic frameworks (MOFs), porous organic polymers (POPs), porous clays, N-doped carbon etc. are explored as versatile and quite elegant way for next-generation CO 2 capture. In this chapter, we will discuss the broad prospect of MOFs, POPs, nanoporous clays and porous carbon for CO 2 storage and sequestration through utilization of their nanospace chemistry.

show abstract

“…Amine modification leads to an increase in CO 2 adsorption capacity and selectivity due to chemical interactions between amine sites and CO 2 . Numerous amines have been investigated for solid amine adsorbents including aminopolymers, aminosilanes, alkanolamines, alkylamines, etc . The nanoporous carbon–polyamine composites display high CO 2 capture capacity because the polyamine dispersed in the nanoporous carbon framework allows CO 2 molecule diffusion and adsorption, whereas the pure polyamine commonly becomes a gel, which hinders the diffusion of CO 2 molecules and interaction with amine groups .…”

Section: Introductionmentioning

confidence: 99%

“…[24] Numerous amines have been investigated for solid amine adsorbents including aminopolymers, aminosilanes, alkanolamines, alkylamines, etc. [25,26] The nanoporous carbon-polyamine composites display high CO 2 capture capacity because the polyamine dispersed in the nanoporous carbon framework allows CO 2 molecule diffusion and adsorption, whereas the pure polyamine commonly becomes a gel, which hinders the diffusion of CO 2 molecules and interaction with amine groups. [27,28] Among the polyamines, polyethyleneimine (PEI) is most commonly used due to its having more amino groups per molecule than other amine-containing compounds, high CO 2 adsorption capacity and good stability at temperatures from 20 to 90°C.…”

Section: Introductionmentioning

confidence: 99%

Highly efficient CO₂ capture with a metal–organic framework‐derived porous carbon impregnated with polyethyleneimine

Salehi

Anbia

2018

Applied Organom Chemis

View full text Add to dashboard Cite

Global warming is considered as one of the great challenges of the twenty‐first century. Application of CO2 capture and storage technologies to flue gas is considered to be a useful method of lessening global warning. Highly porous carbon has played an important role in tackling energy and environmental problems. We attempted to synthesize a highly porous carbon adsorbent by carbonizing a highly crystalline metal–organic framework (MOF) without any carbon precursors and focused on the adsorption of CO2 and CH4 gases and CO2/CH4 selectivity at 298, 323 and 348 K using a volumetric apparatus. The MOF‐derived porous carbon (MDC) was prepared by direct carbonization of MOF‐199 as a template at 900 °C under nitrogen atmosphere. Amino‐impregnated MDC samples exhibited enhanced adsorption capacities by a combination of physical and chemical adsorption. Polyethyleneimine (PEI) was selected as the amine source, which was found to greatly enhance CO2 capture when supported on the porous carbon. Novel PEI‐impregnated MDC nanocomposites were synthesized by wetness impregnation and then characterized using various methods.

show abstract

Porous carbon derived via KOH activation of a hypercrosslinked porous organic polymer for efficient CO2, CH4, H2 adsorptions and high CO2/N2 selectivity

Cited by 90 publications

References 51 publications

Porous Organic Polymers for CO₂ Storage and Conversion Reactions

Porous Organic Polymers for CO₂ Storage and Conversion Reactions

Advances in Porous Adsorbents for CO2 Capture and Storage

Highly efficient CO₂ capture with a metal–organic framework‐derived porous carbon impregnated with polyethyleneimine

Contact Info

Product

Resources

About

Porous carbon derived via KOH activation of a hypercrosslinked porous organic polymer for efficient CO2, CH4, H2 adsorptions and high CO2/N2 selectivity

Cited by 90 publications

References 51 publications

Porous Organic Polymers for CO2 Storage and Conversion Reactions

Porous Organic Polymers for CO2 Storage and Conversion Reactions

Advances in Porous Adsorbents for CO2 Capture and Storage

Highly efficient CO2 capture with a metal–organic framework‐derived porous carbon impregnated with polyethyleneimine

Contact Info

Product

Resources

About

Porous Organic Polymers for CO₂ Storage and Conversion Reactions

Porous Organic Polymers for CO₂ Storage and Conversion Reactions

Highly efficient CO₂ capture with a metal–organic framework‐derived porous carbon impregnated with polyethyleneimine